Gommes Cedric J, Jaksch Sebastian, Frielinghaus Henrich
Jülich Center for Neutron Science, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany.
Jülich Center for Neutron Science at the Heinz Maier Leibnitz Zentrum, Forschungszentrum Jülich GmbH, Lichtenbergstrasse 1, 85747 Garching, Germany.
J Appl Crystallogr. 2021 Nov 25;54(Pt 6):1832-1843. doi: 10.1107/S1600576721010293. eCollection 2021 Dec 1.
Many experimental methods are available for the characterization of nanostructures, but most of them are limited by stringent experimental conditions. When it comes to analysing nanostructures in the bulk or in their natural environment - even as ordinary as water at room temperature - small-angle scattering (SAS) of X-rays or neutrons is often the only option. The rapid worldwide development of synchrotron and neutron facilities over recent decades has opened unprecedented possibilities for using SAS and in a time-resolved way. But, in spite of its huge potential in the field of nanomaterials in general, SAS is covered far less than other characterization methods in non-specialized curricula. Presented here is a rigorous discussion of small-angle scattering, at a technical level comparable to the classical undergraduate coverage of X-ray diffraction by crystals and which contains diffraction as a particular case.
有许多实验方法可用于表征纳米结构,但其中大多数都受到严格实验条件的限制。当涉及到分析块状或自然环境中的纳米结构时——即使是像室温下的水这样普通的环境——X射线或中子的小角散射(SAS)通常是唯一的选择。近几十年来,同步加速器和中子设施在全球范围内的迅速发展为以时间分辨方式使用SAS开辟了前所未有的可能性。但是,尽管SAS在纳米材料领域总体上具有巨大潜力,但在非专业课程中,它的涵盖程度远低于其他表征方法。本文在技术层面上对小角散射进行了严谨的讨论,其水平与晶体X射线衍射的经典本科课程相当,并且将衍射作为一种特殊情况包含在内。