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使用柳叶牛膝对植物功能化还原氧化石墨烯-金纳米复合材料的催化及医学潜力

Catalytic and Medical Potential of a Phyto-Functionalized Reduced Graphene Oxide-Gold Nanocomposite Using Willow-Leaved Knotgrass.

作者信息

El-Maghrabi Nourhan, El-Borady Ola M, Hosny Mohamed, Fawzy Manal

机构信息

Green Technology Group, Environmental Sciences Department, Faculty of Science, Alexandria University, 21511 Alexandria, Egypt.

Institute of Nanoscience and Nanotechnology, Kafrelsheikh University, Kafrelsheikh 33516, Egypt.

出版信息

ACS Omega. 2021 Dec 8;6(50):34954-34966. doi: 10.1021/acsomega.1c05596. eCollection 2021 Dec 21.

Abstract

In the current study, a simple, environmentally friendly, and cost-effective reduced graphene oxide-gold nanoparticle (rGO-AuNP) nanocomposite was successfully phytosynthesized using the aqueous leaf extract of a common weed found on the Nile banks, , for the first time. The phytosynthesis of rGO-AuNPs was first confirmed the color transformation from brown to black as well as throughvarious techniques such as transmission electron microscopy (TEM) and Raman spectroscopy. Two UV-vis peaks at 275 and 530 nm were observed for the nanocomposite with a typical particle size of mostly spherical AuNPs of 15-20 nm. However, other shapes were occasionally detected including rods, triangles, and rhomboids. Existing phytoconstituents such as flavonoids and glycosides in the plant extract were suggested to be responsible for the phytosynthesis of rGO-AuNPs. The excellent catalytic efficacy of rGO-AuNPs against MB degradation was confirmed, and a high antibacterial efficiency against and was also confirmed. Promising antioxidant performance of rGO-AuNPs was also proved. Furthermore, it was concluded that rGO-AuNPs acquired higher efficiency than AuNPs synthesized from the same plant extract in all of the studied applications.

摘要

在当前的研究中,首次成功地利用尼罗河岸上常见杂草的水叶提取物,通过植物合成法制备了一种简单、环保且具有成本效益的还原氧化石墨烯-金纳米颗粒(rGO-AuNP)纳米复合材料。rGO-AuNPs的植物合成首先通过颜色从棕色变为黑色以及透射电子显微镜(TEM)和拉曼光谱等各种技术得到证实。观察到该纳米复合材料在275和530nm处有两个紫外可见峰,典型的颗粒尺寸大多为15-20nm的球形金纳米颗粒。然而,偶尔也会检测到其他形状,包括棒状、三角形和菱形。植物提取物中现有的植物成分如黄酮类化合物和糖苷被认为是rGO-AuNPs植物合成的原因。证实了rGO-AuNPs对亚甲基蓝降解具有优异的催化效果,并且对大肠杆菌和金黄色葡萄球菌也具有较高的抗菌效率。还证明了rGO-AuNPs具有良好的抗氧化性能。此外,得出的结论是,在所有研究的应用中,rGO-AuNPs比从相同植物提取物合成的金纳米颗粒具有更高的效率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e455/8697594/7cb65bb216cd/ao1c05596_0002.jpg

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