College of Chemistry & Pharmacy, Northwest A&F University, Yangling, Shaanxi, 712100, PR China.
College of Chemistry & Pharmacy, Northwest A&F University, Yangling, Shaanxi, 712100, PR China.
Talanta. 2022 Apr 1;240:123200. doi: 10.1016/j.talanta.2021.123200. Epub 2022 Jan 7.
The ongoing poisoning of agricultural products has pushed the security problem to become an important issue. Among them, exceeding the standard rate of pesticide residues is the main factor influencing the quality and security of agricultural products. Moreover, the abuse of pesticides has introduced a large amount of residues in soil and drinking water, which will enter the food chain to the human body, leading to neurological disorders and cancer. Therefore, great efforts have been devoted to developing fluorescent sensors for detecting pesticide in a facile, quickly, sensitive, selective, accurate manner, which exhibit greater advantages than some traditional methods. In this review, we mainly focus on summarizing the non-biological fluorescent probes for organic pesticides detection with the detection limit of micromole to nanomole, including organic functional small molecules, calixarenes and pillararenes, metal organic framework systems, and nanomaterials. Meanwhile, we described the different sensing mechanisms for pesticides detection of these mentioned fluorescent sensors, the detection limit of each pesticide, the application in detecting actual samples, as well as their respective advantages and development prospects associated with present non-biological fluorescent sensors.
农产品持续受到毒害,已将安全问题推至重要议题。其中,农药残留超标是影响农产品质量和安全的主要因素。此外,农药的滥用在土壤和饮用水中引入了大量残留,这些残留将进入食物链进入人体,导致神经紊乱和癌症。因此,人们致力于开发用于简便、快速、灵敏、选择性和准确检测农药的荧光传感器,这比一些传统方法具有更大的优势。在本综述中,我们主要关注总结检测限为微摩尔到纳摩尔的用于有机农药检测的非生物荧光探针,包括有机功能小分子、杯芳烃和柱芳烃、金属有机骨架体系和纳米材料。同时,我们描述了这些荧光传感器对农药检测的不同传感机制、每种农药的检测限、在实际样品检测中的应用,以及与当前非生物荧光传感器相关的各自的优点和发展前景。