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发光纳米材料在农药光学传感中的各种光化学过程探索:关于挑战和最新进展的简要讨论

Exploring Various Photochemical Processes in Optical Sensing of Pesticides by Luminescent Nanomaterials: A Concise Discussion on Challenges and Recent Advancements.

作者信息

Paul Suvendu, Daga Pooja, Dey Nilanjan

机构信息

Department of Chemistry, BITS-Pilani Hyderabad Campus, Shameerpet, Hyderabad, Telangana 500078, India.

Department of Chemistry, Siksha-Bhavana, Visva-Bharati University, Santiniketan, West Bengal 731235, India.

出版信息

ACS Omega. 2023 Nov 13;8(47):44395-44423. doi: 10.1021/acsomega.3c02753. eCollection 2023 Nov 28.

Abstract

Food safety is a burning global issue in this present era. The prevalence of harmful food additives and contaminants in everyday food is a significant cause for concern as they can adversely affect human health. More particularly, among the different food contaminants, the use of excessive pesticides in agricultural products is severely hazardous. So, the optical detection of residual pesticides is an effective strategy to counter the hazardous effect and ensure food safety. In this perspective, nanomaterials have played a leading role in defending the open threat against food safety instigated by the reckless use of pesticides. Now, nanomaterial-based optical detection of pesticides has reached full pace and needs an inclusive discussion. This Review covers the advancement of photoprocess-based optical detection of pesticides categorically using nanomaterials. Here, we have thoroughly dissected the photoprocesses (aggregation and aggregation-induced emission (AIE), charge transfer and intramolecular charge transfer (ICT), electron transfer and photoinduced electron transfer (PET), fluorescence resonance energy transfer (FRET), hydrogen bonding, and inner filter effect) and categorically demarcated their significant role in the optical detection of pesticides by luminescent nanomaterials over the last few years.

摘要

食品安全是当今时代一个亟待解决的全球性问题。日常食品中有害食品添加剂和污染物的普遍存在是一个重大的担忧原因,因为它们会对人类健康产生不利影响。更具体地说,在不同的食品污染物中,农产品中过量使用农药极具危害性。因此,对残留农药进行光学检测是应对这种危害并确保食品安全的有效策略。从这个角度来看,纳米材料在抵御因农药滥用引发的对食品安全的公开威胁方面发挥了主导作用。如今,基于纳米材料的农药光学检测已全面展开,需要进行全面的讨论。本综述全面介绍了使用纳米材料基于光过程的农药光学检测进展。在此,我们深入剖析了光过程(聚集和聚集诱导发光(AIE)、电荷转移和分子内电荷转移(ICT)、电子转移和光致电子转移(PET)、荧光共振能量转移(FRET)、氢键和内滤效应),并明确划分了它们在过去几年中发光纳米材料对农药光学检测的重要作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/65ab/10688216/56ad54ca87b7/ao3c02753_0001.jpg

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