Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, China.
CAS Key Laboratory of Strongly-coupled Quantum Matter Physics, Department of Physics, University of Science and Technology of China, Hefei, China.
Nature. 2022 Apr;604(7904):59-64. doi: 10.1038/s41586-022-04493-8. Epub 2022 Feb 9.
Electronic nematicity, in which rotational symmetry is spontaneously broken by electronic degrees of freedom, has been demonstrated as a ubiquitous phenomenon in correlated quantum fluids including high-temperature superconductors and quantum Hall systems. Notably, the electronic nematicity in high-temperature superconductors exhibits an intriguing entanglement with superconductivity, generating complicated superconducting pairing and intertwined electronic orders. Recently, an unusual competition between superconductivity and a charge-density-wave (CDW) order has been found in the AVSb (A = K, Rb, Cs) family with two-dimensional vanadium kagome nets. Whether these phenomena involve electronic nematicity is still unknown. Here we report evidence for the existence of electronic nematicity in CsVSb, using a combination of elastoresistance measurements, nuclear magnetic resonance (NMR) and scanning tunnelling microscopy/spectroscopy (STM/S). The temperature-dependent elastoresistance coefficient (m minus m) and NMR spectra demonstrate that, besides a C structural distortion of the 2a × 2a supercell owing to out-of-plane modulation, considerable nematic fluctuations emerge immediately below the CDW transition (approximately 94 kelvin) and finally a nematic transition occurs below about 35 kelvin. The STM experiment directly visualizes the C-structure-pinned long-range nematic order below the nematic transition temperature, suggesting a novel nematicity described by a three-state Potts model. Our findings indicate an intrinsic electronic nematicity in the normal state of CsVSb, which sets a new paradigm for revealing the role of electronic nematicity on pairing mechanism in unconventional superconductors.
电子向列相,其中旋转对称性通过电子自由度被自发打破,已被证明是关联量子流体中的一种普遍现象,包括高温超导体和量子霍尔体系。值得注意的是,高温超导体中的电子向列相与超导性表现出一种有趣的纠缠关系,产生了复杂的超导配对和交织的电子有序。最近,在二维钒 kagome 网的 AVSb(A = K、Rb、Cs)家族中,发现了超导性和电荷密度波(CDW)有序之间的一种异常竞争。这些现象是否涉及电子向列相仍不清楚。在这里,我们使用弹性电阻测量、核磁共振(NMR)和扫描隧道显微镜/光谱学(STM/S)的组合,报告了 CsVSb 中存在电子向列相的证据。温度依赖的弹性电阻系数(m 减去 m)和 NMR 谱表明,除了由于面外调制而导致的 2a×2a 超胞的 C 结构畸变之外,相当大的向列波动立即在 CDW 转变(约 94 开尔文)以下出现,最终在约 35 开尔文以下发生向列转变。STM 实验直接可视化了向列转变温度以下 C 结构钉扎的长程向列有序,表明一种新的由三态 Potts 模型描述的向列性。我们的发现表明 CsVSb 正常态中存在固有电子向列相,为揭示电子向列相在非常规超导体配对机制中的作用提供了一个新的范例。