Vidal Alfonso M, Moya Manuel, Alcalá Sonia, Romero Inmaculada, Espínola Francisco
Department Chemical, Environmental and Materials Engineering, Universidad de Jaén, Paraje Las Lagunillas, Edif. B-3, 23071 Jaén, Spain.
Center for Advanced Studies in Earth Sciences, Energy and Environment (CEACTEMA), Universidad de Jaén, 23071 Jaén, Spain.
Antioxidants (Basel). 2022 Jan 21;11(2):204. doi: 10.3390/antiox11020204.
Refined olive oils (ROOs) are commonly enriched with synthetic antioxidants. Antioxidant extracts obtained from natural products can be used to improve the stability of these oils. In this study, ROOs were enriched through the addition of phenolic extracts from olive leaves (OLs) and exhausted olive pomace (EOP). In addition to replacing synthetic antioxidants with natural ones, this results in the valorization of these olive-derived biomasses. The most suitable method for mixing and enriching refined oils was probe-type ultrasonication using lecithin as the emulsifier. Thereafter, the change in the content of antioxidant compounds and the antioxidant capacity of the oils at 25, 35, and 45 °C were studied over 28 and 50 days of storage. The experimental results were fitted using a pseudo-first-order kinetic model. The oxidative stability index of the ROO enriched with a 2 g/L OL extract (70 h) was higher than that of a commercial ROO (46.8 h). Moreover, the oxidative stability index of the refined olive pomace oil (ROPO) enriched with a 2 g/L EOP extract (44.1 h) was higher than that of a commercial ROPO (38.9 h). In addition, the oxidative stabilities and antioxidant capacities of the oils were significantly correlated.
精炼橄榄油(ROO)通常富含合成抗氧化剂。从天然产物中提取的抗氧化剂可用于提高这些油的稳定性。在本研究中,通过添加橄榄叶(OL)和废橄榄果渣(EOP)中的酚类提取物来富集ROO。除了用天然抗氧化剂替代合成抗氧化剂外,这还能使这些源自橄榄的生物质得到增值利用。最适合混合和富集精炼油的方法是使用卵磷脂作为乳化剂的探头式超声处理。此后,研究了在25、35和45℃下储存28天和50天时油中抗氧化化合物含量和抗氧化能力的变化。实验结果采用伪一级动力学模型进行拟合。添加2 g/L OL提取物的ROO的氧化稳定性指数(70小时)高于市售ROO(46.8小时)。此外,添加2 g/L EOP提取物的精炼橄榄果渣油(ROPO)的氧化稳定性指数(44.1小时)高于市售ROPO(38.9小时)。此外,油的氧化稳定性和抗氧化能力显著相关。