Wang Wenxuan, Yu Feihan, Ba Zhichen, Qian Hongbo, Zhao Shuai, Liu Jie, Jiang Wei, Li Jian, Liang Daxin
Key Laboratory of Bio-Based Material Science and Technology (Ministry of Education), Northeast Forestry University, Harbin 150040, China.
Department of Military Facilities, Army Logistics Academy, Chongqing 401331, China.
Polymers (Basel). 2022 Apr 6;14(7):1482. doi: 10.3390/polym14071482.
As one of the hazardous heavy metal ion pollutants, Cr(VI) has attracted much attention in the sewage treatment research field due to its wide distribution range and serious toxicity. In this paper, cellulose fibers were prepared by wet spinning and followed by freeze drying, resulting in large porosity. Subsequently, in-depth sulfhydryl modification was applied with cellulose fibers for efficient and rapid adsorption of Cr(VI). The maximum adsorption capacity of sulfhydryl-modified cellulose fibers to Cr(VI) can reach 120.60 mg g, the adsorption equilibrium can be achieved within 300 s, and its adsorption rate can reach 0.319 mg g s. The results show that the in-depth sulfhydryl-modified cellulose fibers perform excellent adsorption capacity for chromium, and are also available for other heavy metal ions. At the same time, the low cost and environmentally friendly property of the as-synthesized material also demonstrate its potential for practical usage for the treatment of heavy metal ion pollution in waste water.
作为有害重金属离子污染物之一,六价铬(Cr(VI))因其分布范围广和毒性严重,在污水处理研究领域备受关注。本文通过湿法纺丝制备纤维素纤维,随后进行冷冻干燥,使其具有大孔隙率。随后,对纤维素纤维进行深度巯基改性,以实现对Cr(VI)的高效快速吸附。巯基改性纤维素纤维对Cr(VI)的最大吸附容量可达120.60 mg/g,在300 s内可达到吸附平衡,其吸附速率可达0.319 mg/(g·s)。结果表明,深度巯基改性纤维素纤维对铬具有优异的吸附能力,对其他重金属离子也有效。同时,合成材料的低成本和环境友好特性也证明了其在处理废水中重金属离子污染方面的实际应用潜力。