Weinhold Marcel, Klar Peter J
Institute of Experimental Physics I and Center for Materials Research (ZfM), Justus Liebig University Giessen Heinrich-Buff-Ring 16 DE-35392 Giessen Germany
RSC Adv. 2021 Sep 6;11(48):29887-29895. doi: 10.1039/d1ra04982h.
2D materials have been intensively studied for almost two decades and are now exhibiting exceptional properties. Thus, devices that integrate 2D materials offer many novel functionalities that will contribute significantly to the transition into an era beyond 'Moore'. Lithographic methods are key technologies in the context of materials' integration into devices. However, to fully leverage the capabilities of these potential devices, it is vital to keep the integrity of the 2D materials intact and to minimize damage induced by device processing. This requirement is only partially met when employing conventional lithography methods, as they induce structural defects in the delicate materials. We demonstrate that exposing graphene to typical electron doses used in conventional electron beam lithography induces significant defect formation. The defect density is proportional to the electron dose and the structural integrity cannot be fully recovered by thermal annealing. We introduce a novel approach of mild lithography which combines traditional processing methods with a subsequent transfer step of the patterned mask onto the 2D material. We demonstrate that this separation of pattern definition and pattern application allows the lithographic process to be performed without exposing and potentially damaging the 2D material being processed. Finally, as an example relevant in terms of innovative device architectures, we present how the mild lithography approach can be used to achieve ordered arrangements of gold nanoparticles on 2D materials.
二维材料已被深入研究了近二十年,目前正展现出非凡的特性。因此,集成二维材料的器件具有许多新颖的功能,这将极大地推动向“超越摩尔”时代的转变。光刻方法是将材料集成到器件过程中的关键技术。然而,要充分发挥这些潜在器件的能力,保持二维材料的完整性并将器件加工引起的损伤降至最低至关重要。采用传统光刻方法时,这一要求只能部分得到满足,因为它们会在这些脆弱材料中诱发结构缺陷。我们证明,将石墨烯暴露于传统电子束光刻中使用的典型电子剂量会导致大量缺陷形成。缺陷密度与电子剂量成正比,并且通过热退火无法完全恢复结构完整性。我们引入了一种温和光刻的新方法,该方法将传统加工方法与随后将图案化掩模转移到二维材料上的步骤相结合。我们证明,这种图案定义和图案应用的分离使得光刻过程能够在不暴露且潜在不损坏正在加工的二维材料的情况下进行。最后,作为与创新器件架构相关的一个例子,我们展示了温和光刻方法如何用于在二维材料上实现金纳米颗粒的有序排列。