新型手性嵌合光有机催化剂的合成
Syntheses of new chiral chimeric photo-organocatalysts.
作者信息
Lyu Jiyaun, Leone Matteo, Claraz Aurélie, Allain Clémence, Neuville Luc, Masson Géraldine
机构信息
Institut de Chimie des Substances Naturelles, CNRS, Univ. Paris-Saclay 1 Avenue de la Terrasse 91198 Gif-sur-Yvette Cedex France
Université Paris-Saclay, ENS Paris-Saclay, CNRS, PPSM 91190 Gif-sur-Yvette France.
出版信息
RSC Adv. 2021 Nov 15;11(58):36663-36669. doi: 10.1039/d1ra06885g. eCollection 2021 Nov 10.
A new family of chiral chimeric photo-organocatalysts derived from phosphoric acid were synthesized and their spectroscopic and electrochemical properties were investigated. Then, the ability of these photo-activable molecules to catalyse an asymmetric tandem electrophilic β-amination of enecarbamates was evaluated.
合成了一类新的源自磷酸的手性嵌合光有机催化剂，并研究了它们的光谱和电化学性质。然后，评估了这些光可活化分子催化烯氨基甲酸酯不对称串联亲电β-胺化反应的能力。
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