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聚合物包覆的钛酸酯纳米棒刷上的热响应润湿性和表面粗糙度变化实现快速多向液滴传输

Thermo-responsive wettability surface roughness change on polymer-coated titanate nanorod brushes toward fast and multi-directional droplet transport.

作者信息

Okada Kenji, Miura Yoko, Chiya Tomoya, Tokudome Yasuaki, Takahashi Masahide

机构信息

Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University Sakai Osaka 599-8531 Japan

JST, PRESTO 4-1-8 Honcho Kawaguchi Saitama 332-0012 Japan.

出版信息

RSC Adv. 2020 Jul 28;10(47):28032-28036. doi: 10.1039/d0ra05471b. eCollection 2020 Jul 27.

DOI:10.1039/d0ra05471b
PMID:35519096
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9055642/
Abstract

A novel approach for thermo-responsive wettability has been accomplished by surface roughness change induced by thermal expansion of paraffin coated on titanate nanostructures. The surface exhibits thermo-responsive and reversible wettability change in a hydrophobic regime; the surface shows superhydrophobicity with contact angles of ∼157° below 50 °C and ∼118° above 50 °C due to a decrease of surface roughness caused by thermally-expanded paraffin at higher temperatures. Reversible wettability change of ∼40° of a contact angle allows for fast and multi-directional droplet transport. The present approach affords a versatile selection of materials and wide variety of contact angles, promoting both scientific advancement and technology innovation in the field of smart surfaces.

摘要

通过涂覆在钛酸盐纳米结构上的石蜡热膨胀引起的表面粗糙度变化,实现了一种用于热响应润湿性的新方法。该表面在疏水状态下表现出热响应和可逆的润湿性变化;由于高温下热膨胀的石蜡导致表面粗糙度降低,该表面在50℃以下具有约157°的接触角,表现出超疏水性,在50℃以上具有约118°的接触角。约40°接触角的可逆润湿性变化允许快速和多方向的液滴传输。本方法提供了多种材料选择和广泛的接触角范围,促进了智能表面领域的科学进步和技术创新。

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