Raji Reddy Chada, Ganesh Veeramalla, Singh Ajay K
Division of Organic Synthesis and Process Chemistry, CSIR-Indian Institute of Chemical Technology Hyderabad-500007 India
Academy of Scientific and Innovative Research (AcSIR) Ghaziabad 201002 Uttar Pradesh India.
RSC Adv. 2020 Aug 3;10(48):28630-28634. doi: 10.1039/d0ra05288d.
Here, we report controlled - isomeric motion of the functionalized 3-benzylidene-indolin-2-ones under various solvents, temperature, light sources, and most importantly effective enhancement of light irradiance in microfluidic photoreactor conditions. Stabilization of the - isomeric motion is failed in batch process, which might be due to the exponential decay of light intensity, variable irradiation, low mixing, low heat exchange, low photon flux This photo-μ-flow light driven motion is further extended to the establishment of a photostationary state under solar light irradiation.
在此,我们报道了功能化的3-亚苄基吲哚-2-酮在各种溶剂、温度、光源条件下的可控异构运动,最重要的是在微流控光反应器条件下光辐照度的有效增强。在间歇过程中,异构运动的稳定未能实现,这可能是由于光强度的指数衰减、可变照射、低混合、低热交换、低光子通量所致。这种光驱动的微流控运动进一步扩展到在太阳光照射下建立光稳态。