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通过喷涂银纳米线设计用于智能车窗除霜应用的新型可拉伸热致变色透明加热器。

Novel stretchable thermochromic transparent heaters designed for smart window defroster applications by spray coating silver nanowire.

作者信息

Veeramuthu Loganathan, Chen Bo-Yu, Tsai Ching-Yi, Liang Fang-Cheng, Venkatesan Manikandan, Jiang Dai-Hua, Chen Chin-Wen, Cai Xingke, Kuo Chi-Ching

机构信息

Institute of Organic and Polymeric Materials, Research and Development Center of Smart Textile Technology, National Taipei University of Technology 10608 Taipei Taiwan

Institute for Advanced Study, Shenzhen University Shenzhen Guangdong 518060 P. R. China

出版信息

RSC Adv. 2019 Nov 4;9(61):35786-35796. doi: 10.1039/c9ra06508c. eCollection 2019 Oct 31.

Abstract

A productive and novel method for fabricating stretchable transparent heaters with recognised thermochromic properties using commercially available thermochromic ink (TM-55-blue) and silver nanowire (AgNW)-coated polydimethylsiloxane (PDMS) is proposed. Lower resistance, elevated heat generation, and higher transparencies were the expected essential prerequisites for the fabrication of items such as smart windows and window defrosters. AgNW-coated PDMS (hereafter PH devices) satisfied the essential prerequisites but did not produce sufficient color change. In addition to the appreciable electrical and optical characteristics and mechanical robustness, observable color changes represent a critical factor in effortless temperature monitoring by the heating device. Blending TM-55-blue thermochromic ink with PDMS (PBH device) improves the heating rate and color transformation and promotes the ultralow response time appreciably. More notably, it produces a visible transformation from blue to colorless. Color changes visible to the naked eye, ultralow response time, and heating rate represent valuable features for deploying the PBH devices as window defrosters and in smart window applications.

摘要

提出了一种利用市售热致变色墨水(TM - 55 - 蓝色)和银纳米线(AgNW)涂层聚二甲基硅氧烷(PDMS)制造具有公认热致变色特性的可拉伸透明加热器的高效新颖方法。较低的电阻、更高的发热效率和更高的透明度是制造智能窗户和车窗除霜器等物品的预期基本前提条件。AgNW涂层的PDMS(以下简称PH器件)满足基本前提条件,但没有产生足够的颜色变化。除了具有可观的电学和光学特性以及机械坚固性外,可观察到的颜色变化是加热装置轻松进行温度监测的关键因素。将TM - 55 - 蓝色热致变色墨水与PDMS混合(PBH器件)可提高加热速率和颜色转变,并显著缩短超短响应时间。更值得注意的是,它会产生从蓝色到无色的明显转变。肉眼可见的颜色变化、超短响应时间和加热速率是将PBH器件用作车窗除霜器和智能窗户应用的宝贵特性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/376c/9074719/84693e551c8b/c9ra06508c-f1.jpg

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