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碳纳米颗粒催化

Catalysis with carbon nanoparticles.

作者信息

Testa Caterina, Zammataro Agatino, Pappalardo Andrea, Trusso Sfrazzetto Giuseppe

机构信息

Department of Chemical Sciences, University of Catania Viale Andrea Doria 6 Catania Italy 95125

INSTM Udr of Catania Viale Andrea Doria 6 Catania Italy 95125.

出版信息

RSC Adv. 2019 Sep 3;9(47):27659-27664. doi: 10.1039/c9ra05689k. eCollection 2019 Aug 29.

Abstract

Carbon nanoparticles (CNPs) represent a recent class of nanomaterials, based on carbon sp atoms in the inner core. These new nano-dots cover a wide range of application fields: analytical, sensing and biosensing, bioimaging, theranostic, and molecular communication. However, their use as nanocatalysts is relatively new. Although CNPs can be easily synthesized and obtained in good amounts, few reports on their catalytic applications have been reported. This minireview collects the use of these nanoparticles as catalysts highlighting the improvements with respect to the classic catalytic systems. In particular, due to their unique optical and electrical properties, and due to the possibility to cover the external shell with a wide variety of functional groups, CNPs have found catalytic applications in three main classes of reactions: (i) photocatalysis, (ii) acid-base catalysis and (iii) electro catalysis.

摘要

碳纳米颗粒(CNPs)是基于内核中碳原子的一类新型纳米材料。这些新型纳米点涵盖了广泛的应用领域:分析、传感与生物传感、生物成像、治疗诊断以及分子通信。然而,它们作为纳米催化剂的应用相对较新。尽管碳纳米颗粒易于合成且产量可观,但关于其催化应用的报道却很少。本综述收集了这些纳米颗粒作为催化剂的应用,突出了相对于传统催化体系的改进。特别是,由于其独特的光学和电学性质,以及能够用多种官能团覆盖外壳,碳纳米颗粒已在三类主要反应中得到催化应用:(i)光催化,(ii)酸碱催化和(iii)电催化。

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