Moussa Ziad, Judeh Zaher M A, Ahmed Saleh A
Department of Chemistry, College of Science, United Arab Emirates University P.O. Box 15551 Al Ain United Arab Emirates
School of Chemical and Biomedical Engineering, Nanyang Technological University 62 Nanyang Drive, N1.2-B1-14 Singapore 637459
RSC Adv. 2019 Nov 5;9(60):35217-35272. doi: 10.1039/c9ra07094j. eCollection 2019 Oct 28.
This comprehensive review highlights the diverse chemistry and applications of polymer-supported triphenylphosphine (PS-TPP) in organic synthesis since its inception. Specifically, the review describes applications of the preceding reagent in functional group interconversions, heterocycle synthesis, metal complexes and their application in synthesis, and total synthesis of natural products. Many examples are provided from the literature to show the scope and selectivity (regio, stereo, and chemo) in these transformations.
这篇综述文章重点介绍了聚合物负载三苯基膦（PS-TPP）自问世以来在有机合成中多样的化学性质及应用。具体而言，该综述描述了上述试剂在官能团相互转化、杂环合成、金属配合物及其在合成中的应用以及天然产物全合成方面的应用。文中引用了大量文献实例，以展示这些转化反应的适用范围及选择性（区域选择性、立体选择性和化学选择性）。
