Zou Cunlei, Chen Zongning, Guo Enyu, Kang Huijun, Fan Guohua, Wang Wei, Li Rengeng, Zhang Siruo, Wang Tongmin
Key Laboratory of Solidification Control and Digital Preparation Technology (Liaoning Province), School of Material Science and Engineering, Dalian University of Technology Dalian 116024 China
School of Materials Science and Engineering, Harbin Institute of Technology Harbin 150001 China.
RSC Adv. 2018 Aug 31;8(54):30777-30782. doi: 10.1039/c8ra06020g. eCollection 2018 Aug 30.
Due to the contradiction between mechanical properties and electrical conductivity, it is not easy to fabricate materials with both high strength and good wear resistance with favourable electrical conductivity for the application of electrical materials. In addition, strength and wear resistance do not always present a uniform growth trend at the same time. Herein, a novel copper matrix composite reinforced by synthesized ZrB microparticles and nano CuZr precipitates is successfully prepared by a casting method and sequential heat treatments. The Cu/dual-scale particulate composite possesses a desired trade-off of strength, electrical conductivity and wear resistance. ZrB microparticles form from Zr and B elements in copper melts, and nanoscale CuZr precipitates form in the matrix after solid solution and aging treatments. The ZrB microparticles, nano CuZr precipitates, and well-bonded interfaces contribute to a high tensile strength of 591 MPa and superior wear resistance, with a relative electrical conductivity of 83.7% International Annealed Copper Standard.
由于机械性能和导电性之间的矛盾,制造出兼具高强度、良好耐磨性以及适用于电气材料应用的良好导电性的材料并非易事。此外,强度和耐磨性并不总是同时呈现均匀的增长趋势。在此,通过铸造方法和后续热处理成功制备了一种由合成的ZrB微粒和纳米CuZr析出相增强的新型铜基复合材料。这种铜/双尺度颗粒复合材料在强度、导电性和耐磨性之间实现了理想的平衡。ZrB微粒由铜熔体中的Zr和B元素形成,纳米级CuZr析出相在固溶和时效处理后在基体中形成。ZrB微粒、纳米CuZr析出相以及良好结合的界面共同促成了591MPa的高抗拉强度和优异的耐磨性,相对电导率为国际退火铜标准的83.7%。