Program in Environmental and Polymer Science, Inha University, Incheon 22212, South Korea.
Department of Chemistry and Chemical Engineering, Education and Research Center for Smart Energy and Materials, Inha University, Incheon 22212, South Korea.
ACS Macro Lett. 2022 Apr 19;11(4):428-433. doi: 10.1021/acsmacrolett.1c00772. Epub 2022 Mar 14.
Replica molding is one of the most common and low-cost methods for constructing microstructures for various applications, including dry adhesives, optics, tissue engineering, and strain sensors. However, replica molding provides only a single-height microstructure from a mold and master molds produced by an expensive photolithography process are required to prepare microstructures with different heights. Herein, we present a strategy to control the height of micropillars from the same mold by varying the cavity size of the micromold and the viscosity of the photocurable polyimide resin. The height of the constructed micropillar decreases in the case of small microcavities or high viscosity resin. In addition, the height of the micropillar arrays could be arbitrarily patterned by applying a masking technique. We believe that this cost-effective technique can be applied to metasurfaces for manipulation of electromagnetic signal or in biomedical applications including cell-culture and stem-cell differentiation.
复制成型是构建各种应用微结构的最常见和低成本方法之一,包括干式粘合剂、光学、组织工程和应变传感器。然而,复制成型仅能从模具中获得单一高度的微结构,并且需要使用昂贵的光刻工艺来制备具有不同高度的微结构的母模。在此,我们提出了一种通过改变微模具的型腔尺寸和光固化聚酰亚胺树脂的粘度来控制微柱高度的策略。在小的微腔或高粘度树脂的情况下,构建的微柱高度会降低。此外,通过应用掩模技术,可以任意图案化微柱阵列的高度。我们相信,这种具有成本效益的技术可应用于用于操纵电磁信号的超表面或包括细胞培养和干细胞分化的生物医学应用中。