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埃及尼罗河表层底部沉积物和水体中镉金属的环境地球化学与分馏

Environmental Geochemistry and Fractionation of Cadmium Metal in Surficial Bottom Sediments and Water of the Nile River, Egypt.

作者信息

El-Saadani Zozo, Mingqi Wang, He Zhang, Hamukwaya Shindume Lomboleni, Abdel Wahed Mahmoud S M, Abu Khatita Atef

机构信息

Earth Science and Resources Department, China University of Geoscience, Beijing 100083, China.

Geology Department, Faculty of Science, Zagazig University, Zagazig 44519, Egypt.

出版信息

Toxics. 2022 Apr 28;10(5):221. doi: 10.3390/toxics10050221.

Abstract

Heavy metals such as cadmium (Cd) pollute the environment. Heavy metal pollution endangers the Nile River since it serves as an irrigation and freshwater source for the cities and farms that line its banks. Water and sediment samples from the Nile River were tested for Cd content. In addition, a sequential experiment analytical method was performed to determine the metal's relative mobility. According to the data, there is an average of 0.16 mg kg of Cd in sediments. The BeniSuef water treatment plant and brick factory, the iron and steel factory of Helwan, the oil and detergent factory of Sohag, and the discharge of the cement factory in Samalut had the greatest concentration of Cd in their vicinity. According to the risk assessment code, there are four categories of Cd: residual (57.91%), acid-soluble (27.11%), reducible (11.84%), and oxidizable (3.14%). Bioavailable and mobile Cd levels in sediment and water were found in Beni Suef, Aswan; Helwan; Samalut; Sohag; and Helwan. Because the other metal is highly bioavailable, its concentration is not a risk factor at the Samalut station. Cd's toxicity and bioaccumulation make it an extra hazard to aquatic animals and human life. There should be a deterministic approach to monitoring Cd near industrial sources.

摘要

镉(Cd)等重金属污染环境。重金属污染危及尼罗河,因为它是沿岸城市和农场的灌溉水源和淡水来源。对尼罗河的水和沉积物样本进行了镉含量检测。此外,还采用了顺序实验分析方法来确定该金属的相对迁移率。根据数据,沉积物中镉的平均含量为0.16毫克/千克。贝尼苏韦夫水处理厂和砖厂、赫尔万钢铁厂、索哈杰石油和洗涤剂厂以及萨马卢特水泥厂的排放物在其附近镉的浓度最高。根据风险评估代码,镉有四类:残留态(57.91%)、酸溶态(27.11%)、可还原态(11.84%)和可氧化态(3.14%)。在贝尼苏韦夫、阿斯旺、赫尔万、萨马卢特、索哈杰和赫尔万的沉积物和水中发现了生物可利用且可迁移的镉含量。由于其他金属具有高度生物可利用性,其浓度在萨马卢特站不是一个风险因素。镉的毒性和生物累积性使其对水生动物和人类生命构成额外危害。在工业源附近应采用确定性方法监测镉。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9a61/9146415/a7c95910abff/toxics-10-00221-g001.jpg

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