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一种用于气体渗透的低成本多孔聚合物膜。

A Low-Cost Porous Polymer Membrane for Gas Permeation.

作者信息

Haouari Selim, Rodrigue Denis

机构信息

Department of Chemical Engineering, Laval University, 1065 Avenue de la Médecine, Quebec City, QC G1V 0A6, Canada.

出版信息

Materials (Basel). 2022 May 14;15(10):3537. doi: 10.3390/ma15103537.

Abstract

In this work, an efficient technique was used to produce porous membranes for different applications. Polyethylene (PE) was selected for the matrix, while corn starch (CS) was used to create the porous structure via leaching. The membranes were produced by continuous extrusion (blending)-calendering (forming) followed by CS leaching in a 20% aqueous acetic acid solution at 80 °C. A complete characterization of the resulting membranes was performed including morphological and mechanical properties. After process optimization, the gas transport properties through the membranes were determined on the basis of pure gas permeation including CH, CO, O, and N for two specific applications: biogas sweetening (CH/CO) and oxygen-enriched air (O/N). The gas separation results for ideal permeability and selectivity at 25 °C and 1.17 bar (17 psi) show that these membranes are a good starting point for industrial applications since they are low-cost, easy to produce, and can be further optimized.

摘要

在这项工作中,采用了一种高效技术来制备用于不同应用的多孔膜。选择聚乙烯(PE)作为基体,而玉米淀粉(CS)则通过浸出法来形成多孔结构。这些膜通过连续挤出(共混)-压延(成型)制备,随后在80℃的20%乙酸水溶液中进行CS浸出。对所得膜进行了全面表征,包括形态和力学性能。经过工艺优化后,基于纯气体渗透测定了膜的气体传输性能,其中包括针对两种特定应用的CH、CO、O和N:沼气脱硫(CH/CO)和富氧空气(O/N)。在25℃和1.17巴(17磅力/平方英寸)下的理想渗透率和选择性的气体分离结果表明,这些膜是工业应用的良好起点,因为它们成本低、易于生产且可进一步优化。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bf6d/9142927/ee693b812e9f/materials-15-03537-g001.jpg

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