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硅空位(SiV)和锗空位(GeV)色心掺杂的化学气相沉积纳米金刚石的双发射:生长条件的影响

Duo Emission of CVD Nanodiamonds Doped by SiV and GeV Color Centers: Effects of Growth Conditions.

作者信息

Bogdanov Kirill V, Baranov Mikhail A, Feoktistov Nikolay A, Kaliya Ilya E, Golubev Valery G, Grudinkin Sergey A, Baranov Alexander V

机构信息

Center of Information and Optical Technologies, ITMO University, Kronverksky Pr. 49, bldg. A, 197101 St. Petersburg, Russia.

Ioffe Institute, Polytechnicheskaya 26, 194021 St. Petersburg, Russia.

出版信息

Materials (Basel). 2022 May 18;15(10):3589. doi: 10.3390/ma15103589.

DOI:10.3390/ma15103589
PMID:35629616
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9144245/
Abstract

The investigation of the hot filament chemical vapor deposition nanodiamonds with simultaneously embedded luminescent GeV and SiV color centers from solid sources showed that both the absolute and relative intensities of their zero-phonon lines (at 602 and 738 nm) depend on nanodiamond growth conditions (a methane concentration in the CH/H gas mixture, growth temperature, and time). It is shown that a controlled choice of parameters of hot filament chemical vapor deposition synthesis makes it possible to select the optimal synthesis conditions for tailoring bicolor fluorescence nanodiamond labels for imaging biological systems.

摘要

对通过固体源同时嵌入发光的吉电子伏特(GeV)和硅空位(SiV)色心的热灯丝化学气相沉积纳米金刚石的研究表明,其零声子线(602和738纳米处)的绝对强度和相对强度均取决于纳米金刚石的生长条件(CH/H气体混合物中的甲烷浓度、生长温度和时间)。结果表明,通过对热灯丝化学气相沉积合成参数的可控选择,可以为定制用于生物系统成像的双色荧光纳米金刚石标记物选择最佳合成条件。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/beea/9144245/a7f1fc39a8fc/materials-15-03589-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/beea/9144245/1be8f4efe453/materials-15-03589-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/beea/9144245/b4a7e91dd96b/materials-15-03589-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/beea/9144245/f6a804190473/materials-15-03589-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/beea/9144245/a7f1fc39a8fc/materials-15-03589-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/beea/9144245/1be8f4efe453/materials-15-03589-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/beea/9144245/b4a7e91dd96b/materials-15-03589-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/beea/9144245/f6a804190473/materials-15-03589-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/beea/9144245/a7f1fc39a8fc/materials-15-03589-g004.jpg

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本文引用的文献

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Nanomaterials (Basel). 2021 Oct 23;11(11):2814. doi: 10.3390/nano11112814.
2
Multilevel Optical Labeling by Spectral Luminescence Control in Nanodiamond Color Centers.纳米金刚石色心的光谱发光控制实现多层次光学标记。
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On-chip excitation of single germanium vacancies in nanodiamonds embedded in plasmonic waveguides.
结合独特热学和光学特性的多功能核壳结构金刚石纳米颗粒在未来生物应用中的研究
Nanomaterials (Basel). 2023 Dec 12;13(24):3124. doi: 10.3390/nano13243124.
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Materials (Basel). 2022 Nov 29;15(23):8510. doi: 10.3390/ma15238510.
嵌入等离子体波导中的纳米金刚石中单个锗空位的片上激发
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