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使化学工业脱碳的新兴电化学工艺

Emerging Electrochemical Processes to Decarbonize the Chemical Industry.

作者信息

Xia Rong, Overa Sean, Jiao Feng

机构信息

Center for Catalytic Science and Technology, Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, Delaware 19716, United States.

出版信息

JACS Au. 2022 May 3;2(5):1054-1070. doi: 10.1021/jacsau.2c00138. eCollection 2022 May 23.

Abstract

Electrification is a potential approach to decarbonizing the chemical industry. Electrochemical processes, when they are powered by renewable electricity, have lower carbon footprints in comparison to conventional thermochemical routes. In this Perspective, we discuss the potential electrochemical routes for chemical production and provide our views on how electrochemical processes can be matured in academic research laboratories for future industrial applications. We first analyze the CO emission in the manufacturing industry and conduct a survey of state of the art electrosynthesis methods in the three most emission-intensive areas: petrochemical production, nitrogen compound production, and metal smelting. Then, we identify the technical bottlenecks in electrifying chemical productions from both chemistry and engineering perspectives and propose potential strategies to tackle these issues. Finally, we provide our views on how electrochemical manufacturing can reduce carbon emissions in the chemical industry with the hope to inspire more research efforts in electrifying chemical manufacturing.

摘要

电气化是化学工业脱碳的一种潜在方法。与传统热化学路线相比,当由可再生电力驱动时,电化学过程的碳足迹更低。在这篇展望文章中,我们讨论了化学品生产的潜在电化学路线,并就如何在学术研究实验室中使电化学过程成熟以用于未来工业应用发表了我们的看法。我们首先分析制造业中的二氧化碳排放,并对石化生产、氮化合物生产和金属冶炼这三个排放密集度最高的领域的先进电合成方法进行了调查。然后,我们从化学和工程角度确定了化学生产电气化中的技术瓶颈,并提出了解决这些问题的潜在策略。最后,我们就电化学制造如何减少化学工业中的碳排放发表了看法,希望能激发更多关于化学制造电气化的研究工作。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7019/9131369/cb00661757b1/au2c00138_0001.jpg

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