Semiflow Microwave Heating Reactor with Resonator Moving Mechanism Applied to Zeolite Synthesis.

A semiflow microwave (MW) heating reactor similar to a flow reactor system was developed. Slurry raw materials in the reaction tube were heated continuously and cooled rapidly by moving a thin MW resonator instead of flowing slurry raw materials. From highly viscous mother slurries, Linde-type A (LTA) and faujasite (FAU)-type zeolite nanoparticles of small crystal grains were synthesized quickly. Results show that this heating system can synthesize hydroxy-sodalite (SOD)-type zeolite from coal fly ash particles including those larger than 50 μm. Numerical calculations using the COMSOL Multiphysics program revealed the thermal distribution of liquids of various viscosities using the semiflow MW heating reactor.