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用于非裂变 Mo/Tc 发生器的酸功能化中孔 γ-氧化铝的表面修饰。

Surface modification of acid-functionalized mesoporous gamma-alumina for non-fission Mo/Tc generator.

机构信息

Research Center for Radioisotope, Radiopharmaceutical, and Biodosimetry Technology, National Research and Innovation Agency (BRIN), Puspiptek Area, South Tangerang, 15314, Indonesia; Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia, Depok, 16424, Indonesia.

Research Center for Radioisotope, Radiopharmaceutical, and Biodosimetry Technology, National Research and Innovation Agency (BRIN), Puspiptek Area, South Tangerang, 15314, Indonesia.

出版信息

Appl Radiat Isot. 2022 Sep;187:110342. doi: 10.1016/j.apradiso.2022.110342. Epub 2022 Jun 21.

Abstract

Mesoporous gamma-alumina (MGA) was synthesized for neutron-activated Mo adsorbent. Acid functionalization of the MGA was carried out to enhance the Mo adsorption capacity and the Mo breakthrough profile. The acid-treated MGA has a more positive particle charge, rougher surface, smaller particle and pore size, larger surface area, and wider pore distance. The acid-treated MGA has a Mo adsorption capacity of 82.8 ± 6.3 mg Mo/g and resulted in Tc eluate with the Mo breakthrough at the acceptable level.

摘要

介孔γ-氧化铝(MGA)被合成用于中子活化 Mo 吸附剂。对 MGA 进行酸功能化处理以增强 Mo 吸附能力和 Mo 穿透曲线。酸处理的 MGA 具有更正的颗粒电荷、更粗糙的表面、更小的颗粒和孔径、更大的表面积和更宽的孔距。酸处理的 MGA 的 Mo 吸附容量为 82.8±6.3mg Mo/g,并且产生 Tc 洗脱液,其中 Mo 穿透达到可接受的水平。

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