Yao Kaitong, Wu Meng, Chen Dong, Liu Chuanbang, Xu Chen, Yang Donghua, Yao Honghu, Liu Lin, Zheng Yun, Rui Xianhong
School of Materials and Energy, Guangdong University of Technology, Guangzhou, 510006, China.
Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, Jianghan University, Wuhan, 430056, China.
Chem Rec. 2022 Oct;22(10):e202200117. doi: 10.1002/tcr.202200117. Epub 2022 Jul 5.
Alkali metal-ion batteries (SIBs and PIBs) and multivalent metal-ion batteries (ZIBs, MIBs, and AIBs), among the next-generation rechargeable batteries, are deemed appealing alternatives to lithium-ion batteries (LIBs) because of their cost competitiveness. Improving the electrochemical properties of electrode materials can greatly accelerate the pace of development in battery systems to cover the increasing demands of realistic applications. Vanadium tetrasulfide (VS ) is known as a prospective electrode material due to its unique one-dimensional atomic chain structure with a large chain spacing, weak interactions between adjacent chains, and high sulfur content. This review summarizes the synthetic strategies and recent advances of VS as cathodes/anodes for rechargeable batteries. Meanwhile, we describe the structural characteristics and electrochemical properties of VS . And we describe in detail its specific applications in batteries such as SIBs, PIBs, ZIBs, MIBs, and AIBs as well as modification strategies. Finally, the opportunities and challenges of VS in the domain of energy research are described.
碱金属离子电池（SIBs和PIBs）以及多价金属离子电池（ZIBs、MIBs和AIBs）作为下一代可充电电池，因其成本竞争力而被视为锂离子电池（LIBs）颇具吸引力的替代品。改善电极材料的电化学性能能够极大地加快电池系统的发展步伐，以满足现实应用不断增长的需求。四硫化钒（VS ）因其独特的一维原子链结构、较大的链间距、相邻链间较弱的相互作用以及高硫含量，而被认为是一种有前景的电极材料。本综述总结了VS 作为可充电电池阴极/阳极的合成策略和最新进展。同时，我们描述了VS 的结构特征和电化学性能。并且详细阐述了其在SIBs、PIBs、ZIBs、MIBs和AIBs等电池中的具体应用以及改性策略。最后，描述了VS 在能源研究领域的机遇与挑战。
