Rapid Synthesis of Graphdiyne Films on Hydrogel at the Superspreading Interface for Antibacteria.

Graphdiyne (GDY), a two-dimensional (2D) carbon material with diacetylenic linkages (-C≡C-C≡C-) structures, has attracted enormous attention in various fields. However, the controlled synthesis of GDY films is still challenging because of the low alkyne coupling efficiency and out-of-plane growth. Here, we employed a highly efficient Cu(II)-N,N,N',N'-tetramethylethylenediamine (Cu(II)-TMEDA) catalyst and constructed a superspreading liquid/liquid interface on a hydrogel for rapid and controllable synthesis of GDY thin films. GDY films with controllable thickness from 4 to 50 nm and large-scale uniform morphology can be prepared within 2 h at room temperature. The mechanism of growth was revealed to be a nucleation and in-plane extension process. Meanwhile, the as-grown GDY films showed excellent photothermal conversion efficiency, which induces the release of Cu(II) ions from the hydrogel and exhibits high efficiency in synergistic antibacteria.