Bachmann Maja D, Sharpe Aaron L, Baker Graham, Barnard Arthur W, Putzke Carsten, Scaffidi Thomas, Nandi Nabhanila, McGuinness Philippa H, Zhakina Elina, Moravec Michal, Khim Seunghyun, König Markus, Goldhaber-Gordon David, Bonn Douglas A, Mackenzie Andrew P, Moll Philip J W
Max Planck Institute for Chemical Physics of Solids, Dresden, Germany.
School of Physics and Astronomy, University of St Andrews, St Andrews, UK.
Nat Phys. 2022;18(7):819-824. doi: 10.1038/s41567-022-01570-7. Epub 2022 May 9.
In an idealized infinite crystal, the material properties are constrained by the symmetries of the unit cell. The point-group symmetry is broken by the sample shape of any finite crystal, but this is commonly unobservable in macroscopic metals. To sense the shape-induced symmetry lowering in such metals, long-lived bulk states originating from an anisotropic Fermi surface are needed. Here we show how a strongly facetted Fermi surface and the long quasiparticle mean free path present in microstructures of PdCoO yield an in-plane resistivity anisotropy that is forbidden by symmetry on an infinite hexagonal lattice. We fabricate bar-shaped transport devices narrower than the mean free path from single crystals using focused ion beam milling, such that the ballistic charge carriers at low temperatures frequently collide with both of the side walls that define the channel. Two symmetry-forbidden transport signatures appear: the in-plane resistivity anisotropy exceeds a factor of 2, and a transverse voltage appears in zero magnetic field. Using ballistic Monte Carlo simulations and a numerical solution of the Boltzmann equation, we identify the orientation of the narrow channel as the source of symmetry breaking.
在理想化的无限晶体中,材料特性受晶胞对称性的限制。任何有限晶体的样品形状都会破坏点群对称性,但这在宏观金属中通常难以观察到。要感知此类金属中形状诱导的对称性降低,需要源自各向异性费米面的长寿命体态。在此,我们展示了在PdCoO微结构中存在的强刻面费米面和长准粒子平均自由程如何产生面内电阻率各向异性,而在无限六边形晶格上,这种各向异性因对称性而被禁止。我们使用聚焦离子束铣削从单晶制造出宽度小于平均自由程的条形传输器件,使得低温下的弹道电荷载流子频繁与限定通道的两个侧壁碰撞。出现了两种对称性禁止的传输特征:面内电阻率各向异性超过2倍,并且在零磁场中出现横向电压。通过弹道蒙特卡罗模拟和玻尔兹曼方程的数值解,我们确定窄通道的取向是对称性破缺的根源。