Palma Susana I C J, Esteves Carina, Pádua Ana C C S, Alves Cláudia M, Santos Gonçalo M C, Costa Henrique M A, Dionísio Madalena, Gamboa Hugo, Gruber Jonas, Roque Ana C A
UCIBIO, Departamento de Química, FCT-NOVA, Portugal.
LAQV, Departamento de Química, FCT-NOVA, Portugal.
ISOEN 2019 (2019). 2019 Sep 5;2019:1-3. doi: 10.1109/ISOEN.2019.8823178. Epub 2019 May 26.
The materials described in this work result from the self-assembly of liquid crystals and ionic liquids into droplets, stabilized within a biopolymeric matrix. These systems are extremely versatile gels, in terms of composition, and offer potential for fine tuning of both structure and function, as each individual component can be varied. Here, the characterization and application of these gels as sensing thin films in gas sensor devices is presented. The unique supramolecular structure of the gels is explored for molecular recognition of volatile organic compounds (VOCs) by employing gels with distinct formulations to yield combinatorial optical and electrical responses used in the distinction and identification of VOCs.
本研究中所描述的材料是由液晶和离子液体自组装成液滴,并稳定在生物聚合物基质中形成的。就组成而言,这些体系是极具通用性的凝胶,并且由于每个单独的组分都可以变化,因此在结构和功能的精细调节方面具有潜力。在此,介绍了这些凝胶作为气体传感器装置中的传感薄膜的表征和应用。通过使用具有不同配方的凝胶来产生用于区分和识别挥发性有机化合物(VOC)的组合光学和电学响应,探索了凝胶独特的超分子结构对VOC的分子识别作用。