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8-己氧基-2-[(±)-2-(萘-2-基)乙烯基]喹啉的晶体结构

Crystal structure of 8-hex-yloxy-2-[()-2-(naph-thal-en-2-yl)ethen-yl]quinoline.

作者信息

Liu Xiaozhou, Wang Lu, Feng Ying, Cui Deliang, Liu Zhi

机构信息

State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong Province, People's Republic of China.

出版信息

Acta Crystallogr E Crystallogr Commun. 2022 Jul 5;78(Pt 8):770-773. doi: 10.1107/S2056989022006740. eCollection 2022 Aug 1.

Abstract

In the title mol-ecule, CHNO, the naphthalene and quinoline groups are both planar and subtend a dihedral angle of 15.47 (7)°. They are nearly coplanar with the -vinyl bridge and the hex-yloxy chain, which adopts an all- conformation, resulting in transannular bifurcated intra-molecular C-H⋯N,O contact. The crystal structure features γ-packing of the aromatic moieties, while the parallel packing of alkyl chains resembles that of alkanes.

摘要

在标题分子CHNO中,萘基和喹啉基均为平面结构,二者间的二面角为15.47 (7)°。它们与乙烯基桥和己氧基链近乎共面,己氧基链呈全反式构象,从而形成跨环分叉分子内C-H⋯N,O接触。晶体结构的特征是芳香部分呈γ堆积,而烷基链的平行堆积类似于烷烃。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a72/9361378/599fb00cf380/e-78-00770-fig1.jpg

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