Liu Xiaozhou, Wang Lu, Feng Ying, Cui Deliang, Liu Zhi
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong Province, People's Republic of China.
Acta Crystallogr E Crystallogr Commun. 2022 Jul 5;78(Pt 8):770-773. doi: 10.1107/S2056989022006740. eCollection 2022 Aug 1.
In the title mol-ecule, CHNO, the naphthalene and quinoline groups are both planar and subtend a dihedral angle of 15.47 (7)°. They are nearly coplanar with the -vinyl bridge and the hex-yloxy chain, which adopts an all- conformation, resulting in transannular bifurcated intra-molecular C-H⋯N,O contact. The crystal structure features γ-packing of the aromatic moieties, while the parallel packing of alkyl chains resembles that of alkanes.
在标题分子CHNO中,萘基和喹啉基均为平面结构,二者间的二面角为15.47 (7)°。它们与乙烯基桥和己氧基链近乎共面,己氧基链呈全反式构象,从而形成跨环分叉分子内C-H⋯N,O接触。晶体结构的特征是芳香部分呈γ堆积,而烷基链的平行堆积类似于烷烃。