Chen Xiaodong, Gao Xin, Chen Junyu, Liu Yunfeng, Song Chunyu, Liu Wenlei, Wan Yuan, Kong Xiangzheng, Guan Ying, Qiu Zhengsong, Zhong Hanyi, Yang Jinghua, Cui Lifeng
College of Smart Energy, Shanghai Jiao Tong University, Shanghai 200240, PR China.
Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430000, PR China.
ACS Omega. 2022 Aug 1;7(32):27787-27797. doi: 10.1021/acsomega.1c04999. eCollection 2022 Aug 16.
Aiming at the challenge that environmental protection and high-temperature fluid loss reduction performance of the traditional water-based drilling fluid treatment agent are difficult to balance, our studies added psyllium husk as a high-temperature-resistant and environmentally friendly filtrate reducer to a water-based drilling fluid. The composition, physical and chemical properties, and microstructure of psyllium husk are characterized. Then, the effects of psyllium husk after hot rolling at different temperatures on the rheological properties and fluid loss properties of bentonite-based slurry are evaluated. The results show that the psyllium husk added to the bentonite-based slurry can effectively improve the rheological properties and fluid loss properties of the bentonite-based slurry, and the temperature resistance can reach 160 °C. After hot rolling at 160 °C, adding 1 w/v % psyllium husk can reduce the API fluid loss and high-temperature and high-pressure fluid loss of the bentonite-based slurry by 76.04 and 56.91%, respectively, showing excellent fluid loss reduction performance at high temperatures. The branched structure and uronic acid of psyllium husk can inhibit the degradation of its own molecular structure to a certain extent, which is the fundamental reason why psyllium husk still has excellent fluid loss reduction performance at high temperatures. Psyllium husk is expected to replace some traditional synthetic polymers and be used in environmentally friendly high-temperature-resistant water-based drilling fluids.
针对传统水基钻井液处理剂难以兼顾环境保护和高温降滤失性能这一挑战,我们的研究将洋车前子壳作为一种耐高温且环保的降滤失剂添加到水基钻井液中。对洋车前子壳的组成、理化性质及微观结构进行了表征。然后,评估了洋车前子壳在不同温度下热轧后对膨润土基浆体流变性能和滤失性能的影响。结果表明,添加到膨润土基浆体中的洋车前子壳能有效改善膨润土基浆体的流变性能和滤失性能,其耐温性可达160℃。在160℃热轧后,添加1 w/v%的洋车前子壳可使膨润土基浆体的API滤失量和高温高压滤失量分别降低76.04%和56.91%,在高温下表现出优异的降滤失性能。洋车前子壳的支链结构和糖醛酸能在一定程度上抑制其自身分子结构的降解,这是洋车前子壳在高温下仍具有优异降滤失性能的根本原因。洋车前子壳有望替代一些传统合成聚合物,用于环保型耐高温水基钻井液中。