Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.
Department of General and Coordination Chemistry and Crystallography, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University in Lublin, Pl. Marii Curie-Sklodowskiej 3, 20-031 Lublin, Poland.
Int J Mol Sci. 2022 Sep 2;23(17):10005. doi: 10.3390/ijms231710005.
Composite materials very often provide new catalytic, optical or other physicochemical properties not observed for each component separately. Photofunctions in hybrid systems are an interesting topic of great importance for industry. This review presents the recent advances, trends and possible applications of photofunctions of hybrid systems composed of Schiff base metal complexes and metal or semiconductor (nano)materials. We focus on photocatalysis, sensitization in solar cells (DSSC-dye sensitized solar cell), ligand-induced chirality and applications in environmental protection for Cr(VI) to Cr(III) reduction, in cosmetology as sunscreens, in real-time visualization of cellular processes, in bio-labeling, and in light activated prodrug applications.
复合材料常常提供新的催化、光学或其他物理化学性质，这些性质在每个单独的组分中都观察不到。杂化系统中的光功能是一个非常重要的研究课题，对工业具有重要意义。本综述介绍了由席夫碱金属配合物和金属或半导体（纳米）材料组成的杂化系统的光功能的最新进展、趋势和可能的应用。我们专注于光催化、太阳能电池中的敏化（DSSC-染料敏化太阳能电池）、配体诱导手性以及在环境保护中的应用，用于 Cr(VI)到 Cr(III)的还原、在化妆品中作为防晒霜、实时可视化细胞过程、生物标记和光激活前药应用。
