Liu Yang, Guo Naishun, Yin Pengfei, Zhang Chao
Department of Biomedical Engineering, Sun Yat-sen University Guangzhou China 510006
Nanoscale Adv. 2019 Oct 17;1(12):4546-4559. doi: 10.1039/c9na00538b. eCollection 2019 Dec 3.
The facile growth of carbon nanotubes (CNTs) using microwave radiation reveals a new way for the cost-effective synthesis of CNTs for a wide range of applications. In this regard, domestic microwave ovens can be used as convenient plasma reactors to grow CNTs in a very fast, simple, energy-saving and solvent-free manner. The special heating mechanism of microwaves can not only accomplish the fast growth of high-density CNT brushes within tens of seconds, but also eliminate the need for a flammable gaseous carbon source and an expensive furnace. By carefully selecting the substrate and catalyst, low-temperature growth of CNTs can also be achieved on low-melting point organic polymers at atmospheric pressure. Highly localized heating near the catalyst nanoparticles was observed under microwave irradiation, and this phenomenon can be utilized to grow CNTs at desired locations on the substrate to fabricate CNT-based nanoelectronics . Finally, the microwave growth of CNTs is highly adaptive to different carbon sources, substrates and catalysts, showing enormous potential to generate functionalized CNT-based composites for emerging advanced applications.
利用微波辐射轻松生长碳纳米管(CNT)为广泛应用的碳纳米管经济高效合成揭示了一种新方法。在这方面,家用微波炉可作为便捷的等离子体反应器,以非常快速、简单、节能且无溶剂的方式生长碳纳米管。微波的特殊加热机制不仅能在数十秒内实现高密度碳纳米管刷的快速生长,还无需易燃气态碳源和昂贵的熔炉。通过精心选择基底和催化剂,在大气压下也可在低熔点有机聚合物上实现碳纳米管的低温生长。在微波辐射下观察到催化剂纳米颗粒附近的高度局部加热,这一现象可用于在基底上的期望位置生长碳纳米管,以制造基于碳纳米管的纳米电子器件。最后,碳纳米管的微波生长对不同碳源、基底和催化剂具有高度适应性,在生成用于新兴先进应用的功能化碳纳米管基复合材料方面显示出巨大潜力。