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制备具有生物活性玻璃的丙烯酸树脂及其性能表征。

Preparation and characterization of acrylic resins with bioactive glasses.

机构信息

SpofaDental, Markova 238, 506-01, Jicin, Czech Republic.

Department of Advanced Material Technologies, Wroclaw University of Science and Technology, Wrocław, Poland.

出版信息

Sci Rep. 2022 Oct 5;12(1):16624. doi: 10.1038/s41598-022-20840-1.

Abstract

This study aimed to prepare a bioactive acrylic material by adding different types of glasses. Commercially available polymerized acrylic resin was mixed with 10% of four different types of glasses in the powder form and cured. Flexural strength, sorption, and solubility of the samples were tested according to ISO 20795-1:2013. The total number of samples used in the tests were 60. The materials were placed in artificial saliva of pH 4 and 7, and elution was performed for 0, 1, 28, and 42 days. The collected samples were analyzed using inductively coupled plasma atomic emission spectrometry to detect Ca, P, and Si ions and using ion chromatography to detect F ions. The materials obtained after modification with glasses showed lower compressive strength compared with pure polymethyl methacrylate but met the standard requirements. Two glass types showed higher solubility values compared with the value defined by the ISO standard. Biomin C and S53P4 released Ca, P, and Si ions, respectively, after 42 days in artificial saliva. Acrylic resins modified with 10% Biomin C and S53P4 glasses can be a valuable source of Ca and P ions under acid conditions for 28 and 42 days.

摘要

本研究旨在通过添加不同类型的玻璃来制备一种具有生物活性的丙烯酸材料。将市售的聚合丙烯酸树脂与 10%的四种不同类型的玻璃粉末混合并固化。根据 ISO 20795-1:2013 测试样品的弯曲强度、吸水率和溶解度。测试中使用的总样本数为 60 个。将材料置于 pH 值为 4 和 7 的人工唾液中,分别在 0、1、28 和 42 天进行洗脱。用等离子体原子发射光谱法(ICP-AES)分析收集的样品,以检测 Ca、P 和 Si 离子,用离子色谱法(IC)分析 F 离子。用玻璃修饰后的材料的抗压强度与纯聚甲基丙烯酸甲酯相比有所降低,但符合标准要求。两种玻璃类型的溶解度值比 ISO 标准规定的值高。Biomin C 和 S53P4 在人工唾液中分别在 42 天后释放 Ca、P 和 Si 离子。经过 10% Biomin C 和 S53P4 玻璃改性的丙烯酸树脂在 28 和 42 天的酸性条件下可以成为 Ca 和 P 离子的有价值来源。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c7b/9534886/33605ad1147d/41598_2022_20840_Fig1_HTML.jpg

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