Shigenaga Satsuki, Shibata Haruko, Tagami Koto, Kanbara Tadashi, Yajima Tomoko
Department of Chemistry, Ochanomizu University, 2-1-1, Otsuka, Bunkyo-ku, Tokyo 112-8610, Japan.
J Org Chem. 2022 Nov 4;87(21):14923-14929. doi: 10.1021/acs.joc.2c01827. Epub 2022 Oct 6.
The eosin Y-catalyzed hydroperfluoroalkylation of electron-deficient alkenes is described herein. The reaction proceeded smoothly under visible light irradiation and selectively afforded a hydroperfluoroalkylated product. Various perfluoroalkyl bromides and electron-deficient olefins can be used in this reaction, and all chemicals required for this reaction are safe and readily available.
本文描述了曙红Y催化的缺电子烯烃的氢全氟烷基化反应。该反应在可见光照射下顺利进行，选择性地得到氢全氟烷基化产物。各种全氟烷基溴化物和缺电子烯烃可用于该反应，且该反应所需的所有化学品均安全且易于获得。
