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用于现场检测环境中肼的萘基荧光探针。

Naphthalene-based fluorescent probe for on-site detection of hydrazine in the environment.

作者信息

Zeng Conghui, Xu Zhongyong, Song Chao, Qin Tianyi, Jia Tianhao, Zhao Chen, Wang Lei, Liu Bin, Peng Xiaojun

机构信息

Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Material Science and Engineering, Shenzhen University, Shenzhen 518060, PR China.

Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Material Science and Engineering, Shenzhen University, Shenzhen 518060, PR China.

出版信息

J Hazard Mater. 2023 Mar 5;445:130415. doi: 10.1016/j.jhazmat.2022.130415. Epub 2022 Nov 16.

DOI:10.1016/j.jhazmat.2022.130415
PMID:36455322
Abstract

The widespread occurrence of hydrazine residues in the environment, including in water, soil, and organisms, is a potential health threat to humans. Therefore, the development of an efficient method for the detection of hydrazine in environmental samples is highly desirable although it poses a significant challenge. In this study, we designed and synthesized a series of naphthalene-based fluorescent dyes through structural engineering and developed a novel probe for hydrazine detection. The probe could provide a distinct fluorescence response toward hydrazine in aqueous solution with high sensitivity and selectivity. Moreover, paper-based test strips can be easily fabricated using this probe, enabling the portable on-site detection of hydrazine with the aid of a smartphone. Furthermore, we demonstrated that this probe is capable of recognizing hydrazine in various environmental samples, including water, soil, plants, and zebrafish embryos. This research provides a promising tool for the detection of hydrazine in the environment.

摘要

肼残留物在包括水、土壤和生物体在内的环境中广泛存在,这对人类健康构成了潜在威胁。因此,尽管开发一种高效的环境样品中肼的检测方法面临重大挑战,但这一需求十分迫切。在本研究中,我们通过结构工程设计并合成了一系列基于萘的荧光染料,并开发了一种用于肼检测的新型探针。该探针能够在水溶液中对肼产生明显的荧光响应,具有高灵敏度和选择性。此外,使用该探针可以轻松制备纸质测试条,借助智能手机实现肼的便携式现场检测。此外,我们证明了该探针能够识别包括水、土壤、植物和斑马鱼胚胎在内的各种环境样品中的肼。这项研究为环境中肼的检测提供了一种有前景的工具。

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