Palladium(II)-Catalyzed Regioselective Hydroesterification of 1,3-Conjugated Enynes with Aryl Formates.
作者信息
Xiang Xia-Bin, Wang Sheng, Xu Teng, Chen Shanshan
机构信息
Division of Applied Chemistry, School of Natural Sciences, Anhui Agricultural University, Hefei, Anhui 230036, P. R. China.
出版信息
Org Lett. 2023 Feb 3;25(4):587-591. doi: 10.1021/acs.orglett.2c04103. Epub 2023 Jan 19.
PMID:36656106
Abstract
An effective Pd-catalyzed regioselective hydroesterification of 1,3-conjugated enynes with aryl formates was developed. Under the Pd-CyDPEphos catalytic system, the conjugated enynes reacted with phenyl formates and selectively provided the 2-ester-substituted 1,3-dienes in good yields with excellent regioselectivities.
摘要
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