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碳氢(C-H)活化机制与术语的连续统。

The continuum of carbon-hydrogen (C-H) activation mechanisms and terminology.

作者信息

Altus Kristof M, Love Jennifer A

机构信息

Department of Chemistry, The University of British Columbia, Vancouver, BC, V6T 1Z1, Canada.

Department of Chemistry, University of Calgary, 2500 University Drive N.W., Calgary, AB, T2N 1N4, Canada.

出版信息

Commun Chem. 2021 Dec 10;4(1):173. doi: 10.1038/s42004-021-00611-1.

DOI:10.1038/s42004-021-00611-1
PMID:36697593
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9814233/
Abstract

As a rapidly growing field across all areas of chemistry, C-H activation/functionalisation is being used to access a wide range of important molecular targets. Of particular interest is the development of a sustainable methodology for alkane functionalisation as a means for reducing hydrocarbon emissions. This Perspective aims to give an outline to the community with respect to commonly used terminology in C-H activation, as well as the mechanisms that are currently understood to operate for (cyclo)alkane activation/functionalisation.

摘要

作为化学各个领域中快速发展的一个领域,C-H活化/官能团化正被用于获取各种重要的分子目标。特别令人感兴趣的是开发一种可持续的烷烃官能团化方法,作为减少碳氢化合物排放的一种手段。本展望旨在向业界概述C-H活化中常用的术语,以及目前已知的(环)烷烃活化/官能团化的作用机制。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb32/9814233/8e3ba823d24a/42004_2021_611_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb32/9814233/fced1d4126b4/42004_2021_611_Fig1_HTML.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb32/9814233/293482574f33/42004_2021_611_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb32/9814233/fb9cb140d6dc/42004_2021_611_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb32/9814233/cdfd464cb5df/42004_2021_611_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb32/9814233/5321e90e275c/42004_2021_611_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb32/9814233/8e3ba823d24a/42004_2021_611_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb32/9814233/fced1d4126b4/42004_2021_611_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb32/9814233/3ab08c73d7c7/42004_2021_611_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb32/9814233/293482574f33/42004_2021_611_Fig3_HTML.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb32/9814233/5321e90e275c/42004_2021_611_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb32/9814233/8e3ba823d24a/42004_2021_611_Fig7_HTML.jpg

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