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卵磷脂与水混合物中脂质和水的偏比容。

Partial specific volumes of lipid and water in mixtures of egg lecithin and water.

作者信息

White S H, Jacobs R E, King G I

机构信息

Department of Physiology and Biophysics, University of California, Irvine 92717.

出版信息

Biophys J. 1987 Oct;52(4):663-5. doi: 10.1016/S0006-3495(87)83259-9.

DOI:10.1016/S0006-3495(87)83259-9
PMID:3676445
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC1330060/
Abstract

We describe in this paper measurements of the partial specific volumes of lipid (upsilon L) and water (upsilon W) in mechanical mixtures of egg yolk lecithin and water over a range of hydrations (5-55 wt% water) that includes the region at which excess water appears. upsilon L and upsilon W are found to be very nearly 1 cm3/g over the entire range. The water activities of the mixtures were also determined and found to be the same as for lipid deposited as oriented multilayers on solid substrates.

摘要

我们在本文中描述了在一系列水合作用(水含量为5 - 55 wt%)范围内,对蛋黄卵磷脂与水的机械混合物中脂质((v_L))和水((v_W))的偏比容的测量,该范围包括出现过量水的区域。发现在整个范围内(v_L)和(v_W)非常接近1 (cm^3/g)。还测定了混合物的水活度,发现其与以定向多层形式沉积在固体基质上的脂质的水活度相同。

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Partial specific volumes of lipid and water in mixtures of egg lecithin and water.卵磷脂与水混合物中脂质和水的偏比容。
Biophys J. 1987 Oct;52(4):663-5. doi: 10.1016/S0006-3495(87)83259-9.
2
[Thermotropic behavior of liposomes from egg yolk lecithin, hydrogenized egg yolk lecithin and their mixtures].[来自蛋黄卵磷脂、氢化蛋黄卵磷脂及其混合物的脂质体的热致行为]
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3
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本文引用的文献

1
Phase equilibria and structure of dry and hydrated egg lecithin.干态和水合态鸡蛋卵磷脂的相平衡与结构
J Lipid Res. 1967 Nov;8(6):551-7.
2
[Structure of liquid-crystalline phases of different phospholipids, monoglycerides, sphingolipids in the absence or presence of water].[不同磷脂、甘油单酯、鞘脂在无水或有水情况下液晶相的结构]
J Mol Biol. 1967 May 14;25(3):363-82. doi: 10.1016/0022-2836(67)90192-1.
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Studies on phosphatidylcholine vesicles. Determination of partial specific volumes by sedimentation velocity method.磷脂酰胆碱囊泡的研究。用沉降速度法测定偏比容。
J Biol Chem. 1971 Apr 25;246(8):2555-60.
4
Structure and polymorphism of the hydrocarbon chains of lipids: a study of lecithin-water phases.脂质烃链的结构与多态性:卵磷脂 - 水相的研究
J Mol Biol. 1973 Apr 25;75(4):711-33. doi: 10.1016/0022-2836(73)90303-3.
5
The hydration of phospholipids.磷脂的水合作用。
Biochim Biophys Acta. 1974 Jan 23;337(1):79-91. doi: 10.1016/0005-2760(74)90042-3.
6
Hexane dissolved in dioleoyllecithin bilayers has a partial molar volume of approximately zero.溶解在二油酰卵磷脂双层中的己烷的偏摩尔体积约为零。
Biochemistry. 1985 Aug 13;24(17):4637-45. doi: 10.1021/bi00338a024.
7
Molecular packing and area compressibility of lipid bilayers.脂质双层的分子堆积与面积压缩性
Proc Natl Acad Sci U S A. 1985 Oct;82(19):6532-6. doi: 10.1073/pnas.82.19.6532.
8
Hydration force and bilayer deformation: a reevaluation.水合力与双层膜变形:重新评估
Biochemistry. 1986 Jul 15;25(14):4058-66. doi: 10.1021/bi00362a011.
9
X-ray diffraction studies of lecithin bilayers.卵磷脂双层膜的X射线衍射研究。
J Theor Biol. 1976 Oct 21;62(2):447-58. doi: 10.1016/0022-5193(76)90129-6.
10
Measured work of deformation and repulsion of lecithin bilayers.卵磷脂双层膜变形和排斥的测量功
Proc Natl Acad Sci U S A. 1979 Jun;76(6):2750-4. doi: 10.1073/pnas.76.6.2750.