Grushevskaya Halina, Timoshchenko Andrey, Lipnevich Ihor
Physics Department, Belarusian State University, 4 Nezalezhnasti Ave., 220030 Minsk, Belarus.
Nanomaterials (Basel). 2023 Jan 19;13(3):410. doi: 10.3390/nano13030410.
Graphene sheets are a highly radiation-resistant material for prospective nuclear applications and nanoscale defect engineering. However, the precise mechanism of graphene radiation hardness has remained elusive. In this paper, we study the origin and nature of defects induced by gamma radiation in a graphene rolled-up plane. In order to reduce the environmental influence on graphene and reveal the small effects of gamma rays, we have synthesized a novel graphene-based nanocomposite material containing a bilayer of highly aligned carbon nanotube assemblies that have been decorated by organometallic compounds and suspended on nanoporous Al2O3 membranes. The bilayer samples were irradiated by gamma rays from a 137Cs source with a fluence rate of the order of 105 m-2s-1. The interaction between the samples and gamma quanta results in the appearance of three characteristic photon escape peaks in the radiation spectra. We explain the mechanism of interaction between the graphene sheets and gamma radiation using a pseudo-Majorana fermion graphene model, which is a quasi-relativistic N=3-flavor graphene model with a Majorana-like mass term. This model admits the existence of giant charge carrier currents that are sufficient to neutralize the impact of ionizing radiation. Experimental evidence is provided for the prediction that the 661.7-keV gamma quanta transfer enough energy to the electron subsystem of graphene to bring about the deconfinement of the bound pseudo-Majorana modes and involve C atoms in a vortical motion of the electron density flows in the graphene plane. We explain the radiation hardness of graphene by the topological non-triviality of the pseudo-Majorana fermion configurations comprising the graphene charge carriers.
石墨烯片材是一种用于未来核应用和纳米级缺陷工程的高抗辐射材料。然而,石墨烯辐射硬度的确切机制仍然难以捉摸。在本文中,我们研究了石墨烯卷曲平面中由伽马辐射诱导的缺陷的起源和性质。为了减少环境对石墨烯的影响并揭示伽马射线的微小效应,我们合成了一种新型的基于石墨烯的纳米复合材料,其中包含由有机金属化合物修饰并悬浮在纳米多孔Al2O3膜上的高度对齐的碳纳米管组件双层。双层样品用来自137Cs源的伽马射线辐照,通量率约为105 m-2s-1。样品与伽马量子之间的相互作用导致辐射光谱中出现三个特征性的光子逃逸峰。我们使用伪马约拉纳费米子石墨烯模型解释石墨烯片与伽马辐射之间的相互作用机制,该模型是具有类马约拉纳质量项的准相对论N = 3味石墨烯模型。该模型允许存在足以抵消电离辐射影响的巨大电荷载流子电流。为以下预测提供了实验证据:661.7-keV伽马量子将足够的能量传递给石墨烯的电子子系统,从而导致束缚的伪马约拉纳模式的解禁,并使C原子参与石墨烯平面中电子密度流的涡旋运动。我们通过构成石墨烯电荷载流子的伪马约拉纳费米子构型的拓扑非平凡性来解释石墨烯的辐射硬度。