Dipartimento di Chimica, Università degli Studi di Bari "Aldo Moro", Via Orabona, 4, 70126 Bari, Italy.
Centro Interdipartimentale Laboratorio di Ricerca per la Diagnostica dei Beni Culturali, Via Orabona 4, 70126 Bari, Italy.
Molecules. 2023 Jan 20;28(3):1055. doi: 10.3390/molecules28031055.
The wall paintings of five Hellenistic tombs in Apulia were analysed using a multi-technique approach to discern the painting techniques used and contextualise them within the phenomenon of Hellenistic tomb painting in Southern Italy. In particular, the question was asked whether technical knowledge played a role in the reception of Hellenistic artistic models and whether this knowledge was present locally. Raman and IR spectroscopies were used to identify pigments, colourants, and binders; light and electron microscopy were used to determine the structural characteristics of the paint layers and recognise the manufacturing technique. Analyses identified a fresco application for the Tomba dei Cavalieri (Arpi) and a dry application for the Canosian hypogea. The palette-typical for Hellenistic tomb painting in Southern Italy, Etruria and Macedonia-was composed of lime (white), charcoal (black), hematite (red), goethite (yellow), and Egyptian blue (blue). In the Tomba della Nike (Arpi), meanwhile, two particularly refined preparatory layers were observed. The palette was enriched with precious cinnabar and madder lake. The colouring components of the root were mixed with clay and K-alum applied on an additional layer of lime. The use of madder lake and a pink background link the painting to the polychrome Daunian pottery, and the contribution of a local workshop to the decoration of this tomb thus seems plausible.
采用多技术手段分析了普利亚地区五座希腊化时期墓葬的壁画,以辨别所使用的绘画技术,并将其置于意大利南部希腊化时期墓葬绘画的背景下进行研究。特别是,人们提出了这样一个问题,即技术知识是否在希腊化艺术模式的接受中发挥了作用,以及这种知识是否在当地存在。拉曼和红外光谱用于鉴定颜料、着色剂和粘合剂;光学和电子显微镜用于确定油漆层的结构特征并识别制造技术。分析确定了《骑士之墓》(阿尔皮)采用了壁画技术,而卡诺西亚地下墓穴则采用了干壁画技术。调色板——典型的意大利南部、伊特鲁里亚和马其顿的希腊化时期墓葬绘画——由石灰(白色)、木炭(黑色)、赤铁矿(红色)、针铁矿(黄色)和埃及蓝(蓝色)组成。然而,在《胜利之墓》(阿尔皮)中,观察到了两个特别精细的预备层。调色板中还加入了珍贵的朱砂和茜素红。根的着色成分与粘土混合,并在额外的石灰层上施加 K 明矾。茜素红和粉红色背景的使用将绘画与多彩的多纳安陶器联系起来,因此,当地的一个工作室似乎对这座墓葬的装饰做出了贡献。