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碳质小行星(162173)龙宫上的尿嘧啶。

Uracil in the carbonaceous asteroid (162173) Ryugu.

机构信息

Institute of Low Temperature Science (ILTS), Hokkaido University, N19W8, Kita-ku, Sapporo, 060-0819, Japan.

Biogeochemistry Research Center (BGC), Japan Agency for Marine-Earth Science and Technology (JAMSTEC), Natsushima, Yokosuka, 237-0061, Japan.

出版信息

Nat Commun. 2023 Mar 21;14(1):1292. doi: 10.1038/s41467-023-36904-3.

Abstract

The pristine sample from the near-Earth carbonaceous asteroid (162173) Ryugu collected by the Hayabusa2 spacecraft enabled us to analyze the pristine extraterrestrial material without uncontrolled exposure to the Earth's atmosphere and biosphere. The initial analysis team for the soluble organic matter reported the detection of wide variety of organic molecules including racemic amino acids in the Ryugu samples. Here we report the detection of uracil, one of the four nucleobases in ribonucleic acid, in aqueous extracts from Ryugu samples. In addition, nicotinic acid (niacin, a B vitamer), its derivatives, and imidazoles were detected in search for nitrogen heterocyclic molecules. The observed difference in the concentration of uracil between A0106 and C0107 may be related to the possible differences in the degree of alteration induced by energetic particles such as ultraviolet photons and cosmic rays. The present study strongly suggests that such molecules of prebiotic interest commonly formed in carbonaceous asteroids including Ryugu and were delivered to the early Earth.

摘要

隼鸟 2 号采集的近地碳质小行星(162173)龙宫的原始样本使我们能够在不受地球大气和生物圈失控暴露的情况下分析原始的外星物质。可溶性有机物的初始分析团队报告在龙宫样本中检测到了包括外消旋氨基酸在内的多种有机分子。在这里,我们报告了在龙宫样本的水溶液提取物中检测到尿嘧啶,这是核糖核酸中的四种核碱基之一。此外,还检测到烟酸(维生素 B 族成员之一)及其衍生物和咪唑类物质,以寻找含氮杂环分子。在 A0106 和 C0107 之间观察到的尿嘧啶浓度差异可能与由紫外线光子和宇宙射线等高能粒子引起的可能的改变程度有关。本研究强烈表明,包括龙宫在内的碳质小行星中通常形成此类具有前生物意义的分子,并被输送到早期地球。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60a6/10030641/a14da142af02/41467_2023_36904_Fig1_HTML.jpg

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