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傅里叶变换红外光谱法作为识别油料种子成分中脂质独特特征谱带的工具:通过埃塞俄比亚本土沙漠枣果实得到证实。

Fourier transform infrared spectroscopy as a tool for identifying the unique characteristic bands of lipid in oilseed components: Confirmed via Ethiopian indigenous desert date fruit.

作者信息

Mekonnen Kedir Derbie

机构信息

School of Chemical and Mechanical Engineering, Kombolcha Institute of Technology-Wollo University, Wollo, Ethiopia.

出版信息

Heliyon. 2023 Mar 22;9(4):e14699. doi: 10.1016/j.heliyon.2023.e14699. eCollection 2023 Apr.

Abstract

Searching for good sources of value-added lipids that can be utilized for industrial and domestic applications is getting a fast-growing attention. Hence, the exploitation of underutilized fruit species for oil production is of particular care. But, rapid and accurate characterization of oil-bearing biomass before considering it as an alternative source is essential to know the properties of interest which significantly influence biomass conversion. Instead of testing oilseed components to know their lipid reach part via extractive techniques, one of the rapid analysis methods is Fourier transform infrared spectroscopic approach. Thus, this paper aims to identify the unique characteristic bands of lipids in oilseed components confirmed via Ethiopian desert date fruit (i.e., mesocarp, endocarp, kernel and oil). While all parts of the fruit were subjected to oil extraction, it was proved that the only fatty portion containing about 40.32% wt of lipid was in its kernel. Accordingly, the only functional groups observed in the oil-rich part include = C-H stretching at 3006/7 cm in aromatic and olefins of unsaturated fatty acid, symmetrical C-H stretching of aliphatics in the -CH groups at 2853 cm, C-O stretching in esters due to asymmetric vibrations of C-C(=O)-O bonds at 1159/66 cm, and C-H rocking vibration of methylene in alkanes at 718/23 cm.

摘要

寻找可用于工业和家庭应用的优质增值脂质来源正受到越来越多的关注。因此,开发未充分利用的水果品种用于生产油脂尤为重要。但是,在将含油生物质视为替代来源之前,对其进行快速准确的表征对于了解显著影响生物质转化的相关特性至关重要。除了通过萃取技术测试油籽成分以了解其富含脂质的部分外,快速分析方法之一是傅里叶变换红外光谱法。因此,本文旨在确定通过埃塞俄比亚沙漠枣果实(即中果皮、内果皮、果仁及油脂)确认的油籽成分中脂质的独特特征谱带。虽然对果实的所有部分都进行了油脂提取,但事实证明,唯一富含脂肪的部分是其果仁,脂质含量约为40.32%(重量)。相应地,在富含油脂的部分观察到的唯一官能团包括:不饱和脂肪酸的芳香族和烯烃中在3006/7 cm处的=C-H伸缩振动、-CH基团中脂肪族的对称C-H伸缩振动在2853 cm处、由于C-C(=O)-O键的不对称振动导致的酯中的C-O伸缩振动在1159/66 cm处以及烷烃中亚甲基的C-H摇摆振动在718/23 cm处。

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