Recent progress on plant extract-mediated biosynthesis of ZnO-based nanocatalysts for environmental remediation: Challenges and future outlooks.

The plant extract mediated green synthesis of nanomaterials has attracts enormous interest due to its cost-effectiveness, greener, and environmentally friendly. It is also considered as an alternative and facile method in which the phytochemicals can be used as a natural capping and reducing agents and helped to produce nanomaterials with high surface area, different sizes, and shapes. One of the materials fabricated using green methods is zinc oxide (ZnO) semiconductor due to its enormous applications in different field areas. In this review, an overview of recent progress on green synthesized ZnO-based catalysts and various modification methods for the purpose of enhancing the catalytic activity of ZnO and the corresponding structural-activity and interactions towards the removal of pollutants are highlighted. Particularly, the plant extract mediated ZnO-based photocatalysts application for the removal of pollutants via photocatalytic degradation, reduction reaction, and adsorption mechanism are demonstrated. Besides, the opportunities, challenges, and future outlooks of ZnO-based materials for environmental remediation with green and sustainable methods are also included. We believe that this review is a timely and comprehensive review on the recent progress related to plant extract mediated ZnO-based nanocatalysts synthesis and applications for environmental remediation.