Lee Seung Woo, Cho Heyjin, Jang Choel-Min, Huh Myung-Soo, Cho Sung Min
School of Chemical Engineering, Sungkyunkwan University (SKKU), Suwon, 16419, Korea.
Samsung Display Co. Ltd., Yongin, 17113, Korea.
Sci Rep. 2023 Jul 31;13(1):12394. doi: 10.1038/s41598-023-39155-w.
A simple sidewall patterning process for organic-inorganic multilayer thin-film encapsulation (TFE) has been proposed and demonstrated. An AlO thin film grown by atomic layer deposition (ALD) was patterned by adhesion lithography using the difference in interfacial adhesion strength. The difference in interfacial adhesion strength was provided by the vapor-deposited fluoro-octyl-trichloro-silane self-assembled monolayer (SAM) patterns formed by a shadow mask. The sidewall patterning of multilayer TFE was shown possible by repeating the adhesion lithography and the vapor deposition of organic polymer and SAM patterns using shadow masks. The proposed process has the advantage of being able to pattern the blanket ALD-grown AlO thin films by adhesion lithography using a SAM pattern that can be more accurately predefined with a shadow mask.
一种用于有机-无机多层薄膜封装(TFE)的简单侧壁图案化工艺已被提出并得到验证。通过原子层沉积(ALD)生长的AlO薄膜利用界面粘附强度的差异通过粘附光刻进行图案化。界面粘附强度的差异由通过荫罩形成的气相沉积氟代辛基三氯硅烷自组装单分子层(SAM)图案提供。通过重复粘附光刻以及使用荫罩进行有机聚合物和SAM图案的气相沉积,展示了多层TFE侧壁图案化的可能性。所提出的工艺具有能够通过使用可以用荫罩更精确预定义的SAM图案通过粘附光刻对毯式ALD生长的AlO薄膜进行图案化的优点。