Miao Shurong, Nitta Ryosuke, Izawa Seiichiro, Majima Yutaka
Laboratory for Materials and Structures, Institute of Innovative Research, Tokyo Institute of Technology, Yokohama, Kanagawa, 226-8503, Japan.
Joining and Welding Research Institute, Osaka University, Ibaraki, Osaka, 567-0047, Japan.
Adv Sci (Weinh). 2023 Oct;10(29):e2303032. doi: 10.1002/advs.202303032. Epub 2023 Aug 11.
Owing to the emerging trend of non-volatile memory and data-centric computing, the demand for more functional materials and efficient device architecture at the nanoscale is becoming stringent. To date, 2D ferroelectrics are cultivated as channel materials in field-effect transistors for their retentive and switchable dipoles and flexibility to be compacted into diverse structures and integration for intensive production. This study demonstrates the in-plane (IP) ferroelectric memory effect of a 100 nm channel-length 2D ferroelectric semiconductor α-In Se stamped onto nanogap electrodes on Si/SiO under a lateral electric field. As α-In Se forms the bottom contact of the nanogap electrodes, a large memory window of 13 V at drain voltage between ±6.5 V and the on/off ratio reaching 10 can be explained by controlled IP polarization. Furthermore, the memory effect is modulated by the bottom gate voltage of the Si substrate due to the intercorrelation between IP and out-of-plane (OOP) polarization. The non-volatile memory characteristics including stable retention lasting 17 h, and endurance over 1200 cycles suggest a wide range of memory applications utilizing the lateral bottom contact structure.
由于非易失性存储器和以数据为中心的计算的新兴趋势,对纳米级更多功能材料和高效器件架构的需求变得越来越严格。迄今为止,二维铁电体因其具有保持性和可切换偶极子,以及能够被紧凑地制成各种结构并集成用于大规模生产的灵活性,而被培育用作场效应晶体管中的沟道材料。本研究展示了在横向电场下,将沟道长度为100纳米的二维铁电半导体α-In Se压印在Si/SiO上的纳米间隙电极上时的面内(IP)铁电记忆效应。由于α-In Se形成了纳米间隙电极的底部接触,通过可控的面内极化可以解释在漏极电压为±6.5 V之间时13 V的大记忆窗口以及开/关比达到10的现象。此外,由于面内极化与面外(OOP)极化之间的相互关联,记忆效应受到Si衬底底部栅极电压的调制。包括持续17小时的稳定保持和超过1200次循环的耐久性在内的非易失性记忆特性表明,利用横向底部接触结构具有广泛的记忆应用。