He Yingping, Li Lanlan, Su Zhixuan, Xu Lida, Guo Maocheng, Duan Bowen, Wang Wenxuan, Cheng Bo, Sun Daoheng, Hai Zhenyin
Department of Mechanical and Electrical Engineering, Xiamen University, Xiamen 361005, China.
Micromachines (Basel). 2023 Aug 17;14(8):1621. doi: 10.3390/mi14081621.
Current methods for thin film sensors preparation include screen printing, inkjet printing, and MEMS (microelectromechanical systems) techniques. However, their limitations in achieving sub-10 μm line widths hinder high-density sensors array fabrication. Electrohydrodynamic (EHD) printing is a promising alternative due to its ability to print multiple materials and multilayer structures with patterned films less than 10 μm width. In this paper, we innovatively proposed a method using only EHD printing to prepare ultra-micro thin film temperature sensors array. The sensitive layer of the four sensors was compactly integrated within an area measuring 450 μm × 450 μm, featuring a line width of less than 10 μm, and a film thickness ranging from 150 nm to 230 nm. The conductive network of silver nanoparticles exhibited a porosity of 0.86%. After a 17 h temperature-resistance test, significant differences in the performance of the four sensors were observed. Sensor 3 showcased relatively superior performance, boasting a fitted linearity of 0.99994 and a TCR of 937.8 ppm/°C within the temperature range of 20 °C to 120 °C. Moreover, after the 17 h test, a resistance change rate of 0.17% was recorded at 20 °C.
目前制备薄膜传感器的方法包括丝网印刷、喷墨印刷和微机电系统(MEMS)技术。然而,它们在实现线宽小于10μm方面存在局限性,这阻碍了高密度传感器阵列的制造。由于能够打印多种材料和多层结构,且图案化薄膜宽度小于10μm,电液动力(EHD)印刷是一种很有前景的替代方法。在本文中,我们创新性地提出了一种仅使用EHD印刷来制备超微薄膜温度传感器阵列的方法。四个传感器的敏感层紧密集成在一个尺寸为450μm×450μm的区域内,线宽小于10μm,膜厚范围为150nm至230nm。银纳米颗粒的导电网络孔隙率为0.86%。经过17小时的耐温测试,观察到四个传感器的性能存在显著差异。传感器3表现出相对优越的性能,在20℃至120℃的温度范围内,拟合线性度为0.99994,电阻温度系数(TCR)为937.8ppm/℃。此外,在17小时的测试后,20℃时的电阻变化率为0.17%。