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用于高分辨率传感的电流体动力印刷超微银纳米颗粒薄膜温度传感器阵列

Electrohydrodynamic Printed Ultra-Micro AgNPs Thin Film Temperature Sensors Array for High-Resolution Sensing.

作者信息

He Yingping, Li Lanlan, Su Zhixuan, Xu Lida, Guo Maocheng, Duan Bowen, Wang Wenxuan, Cheng Bo, Sun Daoheng, Hai Zhenyin

机构信息

Department of Mechanical and Electrical Engineering, Xiamen University, Xiamen 361005, China.

出版信息

Micromachines (Basel). 2023 Aug 17;14(8):1621. doi: 10.3390/mi14081621.

Abstract

Current methods for thin film sensors preparation include screen printing, inkjet printing, and MEMS (microelectromechanical systems) techniques. However, their limitations in achieving sub-10 μm line widths hinder high-density sensors array fabrication. Electrohydrodynamic (EHD) printing is a promising alternative due to its ability to print multiple materials and multilayer structures with patterned films less than 10 μm width. In this paper, we innovatively proposed a method using only EHD printing to prepare ultra-micro thin film temperature sensors array. The sensitive layer of the four sensors was compactly integrated within an area measuring 450 μm × 450 μm, featuring a line width of less than 10 μm, and a film thickness ranging from 150 nm to 230 nm. The conductive network of silver nanoparticles exhibited a porosity of 0.86%. After a 17 h temperature-resistance test, significant differences in the performance of the four sensors were observed. Sensor 3 showcased relatively superior performance, boasting a fitted linearity of 0.99994 and a TCR of 937.8 ppm/°C within the temperature range of 20 °C to 120 °C. Moreover, after the 17 h test, a resistance change rate of 0.17% was recorded at 20 °C.

摘要

目前制备薄膜传感器的方法包括丝网印刷、喷墨印刷和微机电系统(MEMS)技术。然而,它们在实现线宽小于10μm方面存在局限性,这阻碍了高密度传感器阵列的制造。由于能够打印多种材料和多层结构,且图案化薄膜宽度小于10μm,电液动力(EHD)印刷是一种很有前景的替代方法。在本文中,我们创新性地提出了一种仅使用EHD印刷来制备超微薄膜温度传感器阵列的方法。四个传感器的敏感层紧密集成在一个尺寸为450μm×450μm的区域内,线宽小于10μm,膜厚范围为150nm至230nm。银纳米颗粒的导电网络孔隙率为0.86%。经过17小时的耐温测试,观察到四个传感器的性能存在显著差异。传感器3表现出相对优越的性能,在20℃至120℃的温度范围内,拟合线性度为0.99994,电阻温度系数(TCR)为937.8ppm/℃。此外,在17小时的测试后,20℃时的电阻变化率为0.17%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6b67/10456320/fda00c34df09/micromachines-14-01621-g001.jpg

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