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铜掺杂硒化锡对亚甲基蓝的降解研究

Study on the Degradation of Methylene Blue by Cu-Doped SnSe.

作者信息

Fan Li, Zhu Hongliang, Wang Kaili, Liu Hao, Hu Weina, Xu Xin, Yan Shancheng

机构信息

School of Materials Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023, China.

School of Integrated Circuit Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023, China.

出版信息

Molecules. 2023 Aug 10;28(16):5988. doi: 10.3390/molecules28165988.

Abstract

Treatment of organic wastewater is still a difficult problem to solve. In this paper, Cu-doped SnSe powder was synthesized by a convenient and efficient hydrothermal method. Meanwhile, the degradation effect of different doping concentrations of SnSe on methylene blue was investigated. It was found that at low doping concentrations, the degradation effect on methylene blue was not obvious because Cu was dissolved in the lattice of the SnSe matrix at low concentrations. As the doping concentration increased, SnSe changed from a layered structure to a nanocluster structure with reduced particle size, and a mixed phase of SnSe and CuSnSe appeared. In fact, the degradation effect on methylene blue was significantly enhanced, and we found that the catalytic degradation effect on methylene blue was best at a doping concentration of 10 wt.%.

摘要

有机废水的处理仍然是一个有待解决的难题。本文采用简便高效的水热法合成了铜掺杂的硒化锡粉末。同时,研究了不同掺杂浓度的硒化锡对亚甲基蓝的降解效果。研究发现,在低掺杂浓度下,由于铜在低浓度时溶解在硒化锡基体的晶格中,对亚甲基蓝的降解效果不明显。随着掺杂浓度的增加,硒化锡从层状结构转变为粒径减小的纳米团簇结构,并且出现了硒化锡和铜锡硒的混合相。实际上,对亚甲基蓝的降解效果显著增强,并且我们发现掺杂浓度为10 wt.% 时对亚甲基蓝的催化降解效果最佳。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0356/10459322/169d7c3932b9/molecules-28-05988-g0A1.jpg

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