Orús Pablo, Sigloch Fabian, Sangiao Soraya, De Teresa José María
Instituto de Nanociencia y Materiales de Aragon (INMA), Universidad de Zaragoza-CSIC, Zaragoza, 50009, Spain.
Laboratorio de Microscopias Avanzadas (LMA), Universidad de Zaragoza, Zaragoza, 50018, Spain.
Open Res Eur. 2022 Aug 25;2:102. doi: 10.12688/openreseurope.15000.1. eCollection 2022.
: The use of a focused ion beam to decompose a precursor gas and produce a metallic deposit is a widespread nanolithographic technique named focused ion beam induced deposition (FIBID). However, such an approach is unsuitable if the sample under study is sensitive to the somewhat aggressive exposure to the ion beam, which induces the effects of surface amorphization, local milling, and ion implantation, among others. An alternative strategy is that of focused electron beam induced deposition (FEBID), which makes use of a focused electron beam instead, and in general yields deposits with much lower metallic content than their FIBID counterparts. : In this work, we optimize the deposition of tungsten-carbon (W-C) nanowires by FEBID to be used as electrical contacts by assessing the impact of the deposition parameters during growth, evaluating their chemical composition, and investigating their electrical response. : Under the optimized irradiation conditions, the samples exhibit a metallic content high enough for them to be utilized for this purpose, showing a room-temperature resistivity of 550 μΩ cm and maintaining their conducting properties down to 2 K. The lateral resolution of such FEBID W-C metallic nanowires is 45 nm. : The presented optimized procedure may prove a valuable tool for the fabrication of contacts on samples where the FIBID approach is not advised.
使用聚焦离子束分解前驱体气体并产生金属沉积物是一种广泛应用的纳米光刻技术,称为聚焦离子束诱导沉积(FIBID)。然而,如果所研究的样品对离子束的某种程度的侵蚀性暴露敏感,这种方法就不合适了,因为离子束会引起表面非晶化、局部铣削和离子注入等效应。另一种策略是聚焦电子束诱导沉积(FEBID),它使用聚焦电子束代替离子束,并且通常产生的沉积物的金属含量比FIBID沉积物低得多。
在这项工作中,我们通过评估生长过程中沉积参数的影响、评估其化学成分并研究其电响应,优化了通过FEBID沉积用作电接触的钨碳(W-C)纳米线。
在优化的辐照条件下,样品表现出足够高的金属含量,可用于此目的,室温电阻率为550 μΩ·cm,并且在低至2 K的温度下仍保持其导电性能。这种FEBID W-C金属纳米线的横向分辨率为45 nm。
所提出的优化程序可能被证明是一种有价值的工具,用于在不建议使用FIBID方法的样品上制造接触点。