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利用飞秒激光纹理化技术在不锈钢上设计具有持久抗菌性能的表面,用于“高流量”物体。

Design of Surfaces with Persistent Antimicrobial Properties on Stainless Steel Developed Using Femtosecond Laser Texturing for Application in "High Traffic" Objects.

作者信息

Daskalova Albena, Angelova Liliya

机构信息

Institute of Electronics, Bulgarian Academy of Sciences, 72 Tzarigradsko Chaussee Blvd., 1784 Sofia, Bulgaria.

出版信息

Nanomaterials (Basel). 2023 Aug 23;13(17):2396. doi: 10.3390/nano13172396.

Abstract

Metal-based high-touch surfaces used for diverse applications in everyday use, like handrails, playground grab handles, doorknobs, ATM touch pads, and desks, are the most common targets for pollution with a variety of microbes; there is thus a need to improve their antimicrobial properties, an issue which has become a challenge in recent years, particularly after the COVID-19 pandemic. According to the World Health Organization (WHO), drug-resistant pathogens are one of the main concerns to global health today, as they lead to longer hospital stays and increased medical costs. Generally, the development of antimicrobial surfaces is related to the utilization of chemical methods via deposition on surfaces in the forms of various types of coatings. However, the addition of chemical substances onto a surface can induce unwanted effects, since it causes surface chemistry changes and, in some cases, cannot provide long-lasting results. A novel approach of utilising ultra-short laser radiation for the treatment of metallic surfaces by inducing a variety of micro- and nanostructuration is elaborated upon in the current research, estimating the optimum relation between the wettability and roughness characteristics for the creation of antimicrobial properties for such high-touch surfaces. In the current study, AISI 304-304L stainless steel metal was used as a benchmark material. Surface texturing via laser ablation with femtosecond laser pulses is an effective method, since it enables the formation of a variety of surface patterns, along with the creation of bimodal roughness, in one-step processing. In this investigation, a precise approach toward developing hydrophobic stainless steel surfaces with tunable adherence using femtosecond laser-induced modification is described. The impact of basic femtosecond laser processing parameters, like the scanning velocity, laser energy, and wettability properties of the laser-processed stainless steel samples, are examined. It is identified that the topography and morphology of laser-induced surface structures can be efficiently changed by adapting the laser processing parameters to create structures, which facilitate the transfer of surface properties from extremely low to high surface wettability.

摘要

在日常使用中用于各种用途的金属基高接触表面,如扶手、游乐场抓握把手、门把手、自动取款机触摸板和办公桌,是各种微生物污染的最常见目标;因此,需要提高它们的抗菌性能,近年来这一问题已成为一项挑战,尤其是在新冠疫情之后。根据世界卫生组织(WHO)的说法,耐药病原体是当今全球健康的主要担忧之一,因为它们会导致住院时间延长和医疗成本增加。一般来说,抗菌表面的开发与通过以各种类型涂层的形式沉积在表面上的化学方法的利用有关。然而,在表面添加化学物质会引发不良影响,因为它会导致表面化学变化,并且在某些情况下不能提供持久的效果。当前的研究阐述了一种利用超短激光辐射通过诱导各种微观和纳米结构来处理金属表面的新方法,评估了此类高接触表面产生抗菌性能的润湿性和粗糙度特征之间的最佳关系。在当前的研究中,AISI 304 - 304L不锈钢金属被用作基准材料。通过飞秒激光脉冲进行激光烧蚀的表面纹理化是一种有效的方法,因为它能够在一步加工中形成各种表面图案,并产生双峰粗糙度。在这项研究中,描述了一种使用飞秒激光诱导改性来开发具有可调附着力的疏水不锈钢表面的精确方法。研究了基本的飞秒激光加工参数,如扫描速度、激光能量以及激光加工不锈钢样品的润湿性的影响。研究发现,通过调整激光加工参数来创建结构,可以有效地改变激光诱导表面结构的形貌和形态,从而有助于将表面性质从极低表面润湿性转变为高表面润湿性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcdf/10489816/9926e1ebfbe1/nanomaterials-13-02396-g012.jpg

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