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环保制备的还原氧化石墨烯的可调谐光学和半导体特性

Tunable optical and semiconducting properties of eco-friendly-prepared reduced graphene oxide.

作者信息

Tene Talia, Jiménez-Gaona Yuliana, Campoverde-Santos Diana Katherine, Cevallos Yesenia, La Pietra Matteo, Vacacela Gomez Cristian, Scarcello Andrea, Straface Salvatore, Caputi Lorenzo S, Bellucci Stefano

机构信息

Department of Chemistry, Universidad Técnica Particular de Loja, Loja, Ecuador.

Facultad de Ciencias Pecuarias, Escuela Superior Politécnica de Chimborazo (ESPOCH), Riobamba, Ecuador.

出版信息

Front Chem. 2023 Aug 31;11:1267199. doi: 10.3389/fchem.2023.1267199. eCollection 2023.

Abstract

Wide bandgap oxidized graphenes have garnered particular interest among the materials explored for these applications because of their exceptional semiconducting and optical properties. This study aims to investigate the tunability of the related properties in reduced graphene oxide (rGO) for potential use in energy conversion, storage, and optoelectronic devices. To accomplish this, we scrutinized crucial parameters of the synthesis process such as reduction time and temperature. Our findings demonstrate that controlling these parameters makes it possible to customize the optical bandgap of reduced graphene oxide within a range of roughly 2.2 eV-1.6 eV. Additionally, we observed that reduced graphene oxide has strong and superior absorption in the visible region, which is attributable to the existence of OFGs and defects. Notably, our results indicate that the absorption coefficients of reduced graphene oxide are up to almost three times higher (7426 ml mg m) than those observed in dispersions of exfoliated graphene and graphene oxide (GO). To complement our findings, we employed several spectroscopic and morphological characterizations, including scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and electrical measurements. The implications of our results are significant for the development and design of future semiconductors for energy conversion and optoelectronic applications.

摘要

宽带隙氧化石墨烯因其卓越的半导体和光学性能,在用于这些应用的材料中引起了特别关注。本研究旨在探究还原氧化石墨烯(rGO)相关性能的可调性,以用于能量转换、存储及光电器件。为实现这一目标,我们仔细研究了合成过程的关键参数,如还原时间和温度。我们的研究结果表明,控制这些参数能够在约2.2电子伏特至1.6电子伏特的范围内定制还原氧化石墨烯的光学带隙。此外,我们观察到还原氧化石墨烯在可见光区域具有强烈且优异的吸收,这归因于氧功能团(OFGs)和缺陷的存在。值得注意的是,我们的结果表明,还原氧化石墨烯的吸收系数比在剥离石墨烯和氧化石墨烯(GO)分散体中观察到的吸收系数高出近三倍(7426毫升毫克米)。为补充我们的研究结果,我们采用了多种光谱和形态表征方法,包括扫描电子显微镜(SEM)、能量色散X射线光谱(EDS)、X射线衍射(XRD)以及电学测量。我们的研究结果对于未来用于能量转换和光电器件应用的半导体的开发和设计具有重要意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c292/10501135/01691e6b01db/fchem-11-1267199-g001.jpg

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