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氧化石墨烯的光学性质。

Optical properties of graphene oxide.

作者信息

Tene Talia, Guevara Marco, Benalcázar Palacios Freddy, Morocho Barrionuevo Tania Paulina, Vacacela Gomez Cristian, Bellucci Stefano

机构信息

Department of Chemistry, Universidad Técnica Particular de Loja, Loja, Ecuador.

Facultad de Ingeniería Mecánica, Escuela Superior Politécnica de Chimborazo (ESPOCH), Riobamba, Ecuador.

出版信息

Front Chem. 2023 Jul 20;11:1214072. doi: 10.3389/fchem.2023.1214072. eCollection 2023.

DOI:10.3389/fchem.2023.1214072
PMID:37547907
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10397392/
Abstract

The study of the optical properties of graphene oxide (GO) is crucial in designing functionalized GO materials with specific optical properties for various applications such as (bio) sensors, optoelectronics, and energy storage. The present work aims to investigate the electronic transitions, optical bandgap, and absorption coefficient of GO under different conditions. Specifically, the study examines the effects of drying times ranging from 0 to 120 h while maintaining a fixed temperature of 80°C and low temperatures ranging from 40 to 100, with a constant drying time of 24 h. Our findings indicate that exposing the GO sample to a drying time of up to 120 h at 80°C can lead to a reduction in the optical bandgap, decreasing it from 4.09 to 2.76 eV. The transition was found to be the most affected, shifting from approximately 230 nm at 0 h to 244 nm after 120 h of drying time. Absorption coefficients of 3140-5507 ml mg m were measured, which are similar to those reported for exfoliated graphene dispersions but up to two times higher, confirming the improved optical properties of GO. Our findings can provide insights into determining the optimal temperature and duration required for transforming GO into its reduced form for a specific application through extrapolation. The study is complemented by analyzing the elemental composition, surface morphology change, and electrical properties.

摘要

氧化石墨烯(GO)光学性质的研究对于设计具有特定光学性质的功能化GO材料至关重要,这些材料可用于各种应用,如(生物)传感器、光电子学和能量存储。本工作旨在研究不同条件下GO的电子跃迁、光学带隙和吸收系数。具体而言,该研究考察了在保持80°C固定温度的情况下,干燥时间从0到120小时的影响,以及在干燥时间恒定为24小时的情况下,40到100的低温的影响。我们的研究结果表明,将GO样品在80°C下干燥长达120小时会导致光学带隙减小,从4.09 eV降至2.76 eV。发现跃迁受到的影响最大,从干燥0小时时的约230 nm位移至干燥120小时后的244 nm。测量得到的吸收系数为3140 - 5507 ml mg m,与报道的剥离石墨烯分散体的吸收系数相似,但高出两倍,证实了GO光学性质的改善。我们的研究结果可为通过外推法确定将GO转化为其特定应用的还原形式所需的最佳温度和持续时间提供见解。该研究通过分析元素组成、表面形态变化和电学性质得到补充。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/59aa/10397392/1ce6b2fb8cf4/fchem-11-1214072-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/59aa/10397392/f05851852e87/fchem-11-1214072-g007.jpg
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