Suppr超能文献

源自混合鸡蛋和大米废料的原位氮、氧共掺杂纳米多孔碳用作绿色超级电容器

In Situ N, O Co-Doped Nanoporous Carbon Derived from Mixed Egg and Rice Waste as Green Supercapacitor.

作者信息

Qin Shumeng, Liu Peiliang, Wang Jieni, Liu Chenxiao, Zhang Shuqin, Tian Yijun, Zhang Fangfang, Wang Lin, Cao Leichang, Zhang Jinglai, Zhang Shicheng

机构信息

Miami College, Henan University, Kaifeng 475004, China.

College of Chemistry and Molecular Sciences, Henan University, Kaifeng 475004, China.

出版信息

Molecules. 2023 Sep 9;28(18):6543. doi: 10.3390/molecules28186543.

Abstract

The conversion of nitrogen-oxygen-rich biomass wastes into heteroatomic co-doped nanostructured carbons used as energy storage materials has received widespread attention. In this study, an in situ nitrogen-oxygen co-doped porous carbon was prepared for supercapacitor applications via a two-step method of pre-carbonization and pyrolytic activation using mixed egg yolk/white and rice waste. The optimal sample (YPAC-1) was found to have a 3D honeycomb structure composed of abundant micropores and mesopores with a high specific surface area of 1572.1 m g, which provided abundant storage space and a wide transport path for electrolyte ions. Notably, the specific capacitance of the constructed three-electrode system was as high as 446.22 F g at a current density of 1 A g and remained above 50% at 10 A g. The capacitance retention was 82.26% after up to 10,000 cycles. The symmetrical capacitor based on YPAC-1 with a two-electrode structure exhibited an energy density of 8.3 Wh kg when the power density was 136 W kg. These results indicate that porous carbon materials prepared from mixed protein and carbohydrate waste have promising applications in the field of supercapacitors.

摘要

将富含氮氧的生物质废物转化为用作储能材料的杂原子共掺杂纳米结构碳受到了广泛关注。在本研究中,通过使用蛋黄/蛋白和稻壳废料的两步预碳化和热解活化方法,制备了用于超级电容器应用的原位氮氧共掺杂多孔碳。发现最佳样品(YPAC-1)具有由丰富的微孔和介孔组成的三维蜂窝结构,比表面积高达1572.1 m²/g,为电解质离子提供了丰富的存储空间和宽阔的传输路径。值得注意的是,构建的三电极系统在电流密度为1 A/g时比电容高达446.22 F/g,在10 A/g时仍保持在50%以上。经过多达10000次循环后,电容保持率为82.26%。基于YPAC-1的具有两电极结构的对称电容器在功率密度为136 W/kg时能量密度为8.3 Wh/kg。这些结果表明,由混合蛋白质和碳水化合物废料制备的多孔碳材料在超级电容器领域具有广阔的应用前景。

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验